Thermophysical properties of the binary mixtures (1,8-cineole + 1-alkanol) at T = (298.15 and 313.15) K and at atmospheric pressure

作者: P. Alfaro , E. Langa , J.F. Martínez-López , J.S. Urieta , A.M. Mainar

DOI: 10.1016/J.JCT.2009.08.016

关键词: Speed of soundRefractionEnthalpyChemistryUNIFACRefractive indexIntermolecular forceThermodynamicsMolar volumeAtmospheric pressure

摘要: This work presents the measurements of density, speed sound, refractive index and enthalpy binary mixtures containing {1,8-cineole + 1-alkanol (ethanol, 1-propanol, 1-butanol, 1-pentanol)} at two temperatures (298.15 313.15) K atmospheric pressure. The determination excess molar volume, sound deviation, refraction, refraction isentropic compressibility, are also given. Redlich–Kister equation was used to fit these derivate properties. experimental data constituent binaries were analysed discuss nature strengths intermolecular interactions. Eventually some models, SAFT PC-SAFT for Free Length Collision Factor Gladstone-Dale Arago-Biot index, UNIFAC enthalpy, among others, successfully applied.

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