Derivatization and in situ metallation of phthalocyanines using click chemistry
作者： Yusuf Yılmaz , M. Kasım Şener , İbrahim Erden , Ulvi Avcıata
DOI: 10.1016/J.POLY.2009.07.033
关键词: Salt (chemistry) 、 Chemistry 、 Propargyl bromide 、 Organic chemistry 、 In situ 、 Derivatization 、 Click chemistry 、 Potassium 、 Phthalocyanine
摘要: Abstract Dialkyl (3,4-dicyanophenyl)propargylmalonates were prepared by the reaction of propargyl bromide and potassium salt dialkyl-3,4-dicyanophenylmalonates. A cyclotetramerization was achieved in pentanol presence DBU without protective/deprotective chemistry, affording peripherally tetrasubstituted alkynyl phthalocyanines. Subsequently, situ metallation ‘clicking’ employed for first time as an efficient quantitative route to tetratriazole-functionalized
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