Simultaneous Determination of Nickel and Cobalt Using a Solid Bismuth Vibrating Electrode by Adsorptive Cathodic Stripping Voltammetry
作者： Georgina M. S. Alves , Júlia M. C. S. Magalhães , Helena M. V. M. Soares
关键词: Cobalt 、 Square wave 、 Cathodic stripping voltammetry 、 Electrode 、 Voltammetry 、 Detection limit 、 Chemistry 、 Bismuth 、 Analytical chemistry 、 Nickel 、 Inorganic chemistry 、 Electrochemistry
摘要: A simple, fast, sensitive and greener voltammetric procedure for simultaneous analysis of nickel (Ni) cobalt (Co) by square wave adsorptive cathodic stripping voltammetry (SW-AdCSV) using a solid bismuth vibrating electrode is presented the first time. The enables to determine Ni together with Co, in ammonia buffer 0.1 M (pH 9.2) presence oxygen, involves an accumulation metal-dimethylglyoxime (Ni-DMG Co-DMG) complexes on surface. For detection limits, obtained 30 s time, were 0.6 1.0 µg L−1, respectively. method was free metals (Cd2+, Cr3+, Cr6+, Cu2+, Fe3+ Pb2+ up 50 µg L−1, Al3+ Mn2+ 500 µg L−1; Zn2+ 300 µg L−1) interferences concentrations mentioned brackets. proposed validated determination Co certified reference surface river waters good results.
sci-hub.se 参考文章(45)
Katarzyna Tyszczuk, Mieczyslaw Korolczuk, Fast Simultaneous Adsorptive Stripping Voltammetric Determination of Ni(II) and Co(II) at Lead Film Electrode Plated on Gold Substrate Electroanalysis. ,vol. 19, pp. 1539- 1542 ,(2007) , 10.1002/ELAN.200703880
Emily A Hutton, Božidar Ogorevc, Samo B Hočevar, Frances Weldon, Malcolm R Smyth, Joseph Wang, An introduction to bismuth film electrode for use in cathodic electrochemical detection Electrochemistry Communications. ,vol. 3, pp. 707- 711 ,(2001) , 10.1016/S1388-2481(01)00240-5
Maria Pesavento, Giancarla Alberti, Raffaela Biesuz, Analytical methods for determination of free metal ion concentration, labile species fraction and metal complexation capacity of environmental waters: A review Analytica Chimica Acta. ,vol. 631, pp. 129- 141 ,(2009) , 10.1016/J.ACA.2008.10.046
Iwona Rutyna, Mieczysław Korolczuk, Catalytic Adsorptive Stripping Voltammetry of Cobalt in the Presence of Nitrite at an In Situ Plated Bismuth Film Electrode Electroanalysis. ,vol. 23, pp. n/a- n/a ,(2010) , 10.1002/ELAN.201000592
Ivan Švancara, Chad Prior, Samo B. Hočevar, Joseph Wang, A Decade with Bismuth‐Based Electrodes in Electroanalysis Electroanalysis. ,vol. 22, pp. 1405- 1420 ,(2010) , 10.1002/ELAN.200970017
Miriam Adamovski, Agnieszka Zając, Peter Gründler, Gerd-Uwe Flechsig, Self-assembled monolayers on bismuth electrodes Electrochemistry Communications. ,vol. 8, pp. 932- 936 ,(2006) , 10.1016/J.ELECOM.2006.03.031
Christos Kokkinos, Anastasios Economou, Ioannis Raptis, Microfabricated disposable lab-on-a-chip sensors with integrated bismuth microelectrode arrays for voltammetric determination of trace metals Analytica Chimica Acta. ,vol. 710, pp. 1- 8 ,(2012) , 10.1016/J.ACA.2011.10.048
A ECONOMOU, A VOULGAROPOULOS, On-line stripping voltammetry of trace metals at a flow-through bismuth-film electrode by means of a hybrid flow-injection/sequential-injection system Talanta. ,vol. 71, pp. 758- 765 ,(2007) , 10.1016/J.TALANTA.2006.05.021
Miriam Bučková, Peter Gründler, Gerd-Uwe Flechsig, Adsorptive Stripping Voltammetric Detection of Daunomycin at a Bismuth Bulk Electrode Electroanalysis. ,vol. 17, pp. 440- 444 ,(2005) , 10.1002/ELAN.200403178
Omar El Tall, Daniel Beh, Nicole Jaffrezic-Renault, Olivier Vittori, Electroanalysis of some nitro-compounds using bulk bismuth electrode International Journal of Environmental Analytical Chemistry. ,vol. 90, pp. 40- 48 ,(2010) , 10.1080/03067310902871265