Thermal stability of cordierite catalyst supports contaminated by Fe2O3, ZnO and V2O5

作者: Paolo Scardi , Natale Sartori , Angelo Giachello , Pier Paolo Demaestri , Francesco Branda

DOI: 10.1016/0955-2219(94)90036-1

关键词: SpinelAluminateInorganic chemistryAluminium oxidesZincCatalyst supportMaterials scienceCordieriteThermal stabilityThermal treatmentMaterials ChemistryCeramics and Composites

摘要: Abstract The effect of pollution diesel particulate filters on their thermal and chemical stability has been studied. Commercial cordierite supports were contaminated, separately, by Fe 2 O 3 , ZnO V 5 evolution after treatment in the range 800°C to 1200°C was followed XRD SEM. presence had little effect, whereas reacted completely even at lowest studied temperature, giving crystalline silica aluminium magnesium vanadates; formation a zinc silicate, aluminate with spinel structure glassy phase observed above 1000°C ZnO-contaminated samples. differences reactivity nature reaction products explained taking into account low melting point its acidic character. microstructural changes correlated mechanical properties supports.

参考文章(6)
Y.H. Kim, J.P. Mercurio, C. Gault, Synthesis, formation mechanisms and polymorphism of iron and/or alkali-substituted cordierites Ceramics International. ,vol. 11, pp. 27- 31 ,(1985) , 10.1016/S0272-8842(85)90018-5
Paolo Scardi, Natale Sartori, Angelo Giachello, Pier Paolo Demaestri, Francesco Branda, Influence of calcium oxide and sodium oxide on the microstructure of cordierite catalyst supports Ceramics International. ,vol. 19, pp. 105- 111 ,(1993) , 10.1016/0272-8842(93)90082-3
V. J. Pilletteri, E. D. Case, T. Negas, Laser surface melting and cutting of cordierite substrates Journal of Materials Science Letters. ,vol. 9, pp. 133- 136 ,(1990) , 10.1007/BF00727694
R. L. Jones, C. E. Williams, S. R. Jones, Reaction of Vanadium Compounds with Ceramic Oxides Journal of The Electrochemical Society. ,vol. 133, pp. 227- 230 ,(1986) , 10.1149/1.2108530
I. O. Owate, R. Freer, The electrical properties of some cordierite glass ceramics in the system MgO-Al2O3-SiO2-TiO2 Journal of Materials Science. ,vol. 25, pp. 5291- 5297 ,(1990) , 10.1007/BF00580163
L. Agostini, G. de Portu, S. Guicciardi, C. Borello, P. P. Demaestri, A. Giachello, Characteristics of Porous Cordierite Traps Intentionally Contaminated with Calcium and Zinc Springer Netherlands. pp. 1154- 1161 ,(1992) , 10.1007/978-94-011-2882-7_130