An intramolecular H3O2 bridge as the resting form of an active metal-bound hydroxide in a dinuclear zinc(II) complex

作者: Franc Meyer , Peter Rutsch

DOI: 10.1039/A800412I

关键词: Polymer chemistryPhotochemistryReactivity (chemistry)ChemistryIntramolecular forceBridge (interpersonal)MetalZincHydroxide

摘要: An intramolecular Zn–O2H3–Zn bridge as a complexed form of metal-bound hydroxide exhibits enhanced reactivity compared to the related Zn–OH–Zn unit, illustrated by reaction with CO2.

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