A reinvestigation of the temperature dependence of the rate constant for the reaction O + O2 + M O3 + M (for M = O2, N2, and Ar) by the flash photolysis resonance fluorescence technique
作者： Odo Klais , Philip C. Anderson , Michael J. Kurylo
关键词: Chemistry 、 Kinetics 、 Oxygen 、 Reaction rate constant 、 Molecule 、 Atmospheric temperature range 、 Analytical chemistry 、 Combination reaction 、 Flash photolysis 、 Resonance fluorescence
摘要: The flash photolysis resonance fluorescence technique has been used to reinvestigate the kinetics of oxygen atom–oxygen molecule combination reaction. Third-order rate constants for O2, N2, and Ar as deactivant molecules were determined over temperature range 219–368 K. results presented herein are most extensive data sets available atmospheric modeling formulate a recommendation such purposes. recommended expressions or Comparisons these with existing literature presented.
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