Studies of reactions on metal-impregnated charcoal: Characterization and the thermal desorption of water
作者： M.C. Biesinger , N.S. McIntyre , I. Bello , S. Liang
DOI: 10.1016/S0008-6223(96)00154-6
关键词: Copper 、 Adsorption 、 Charcoal 、 Metal 、 Transition metal 、 Inorganic chemistry 、 Mass spectrometry 、 X-ray photoelectron spectroscopy 、 Chemistry 、 Thermal desorption 、 Analytical chemistry
摘要: Abstract Copper- and chromium-impregnated non-impregnated charcoals have been characterized by X-ray photoelectron spectroscopy scanning electron microscopy, showing the composition distribution of elements in charcoal substrate. Water (as D2O) was reacted with dried its gradual thermal desorption studied mass spectrometry. The impregnated retains substantially more water over a wider temperature span. It is suggested that Cr3+, particular, increases number high-energy adsorption sites. Thermal also results decomposition metal hydroxides reduction Cu2+ to Cu+ Cr6+ Cr3+.
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