Polarizable polymer chain under external electric field: Effects of many-body electrostatic dipole correlations

作者: Yu. A. Budkov , A. L. Kolesnikov

DOI: 10.1140/EPJE/I2016-16110-X

关键词: DipoleElectric dipole transitionField theory (psychology)PolarizabilityPhysicsPolymerChain (algebraic topology)Molecular physicsElectric fieldElectromagnetic coilCondensed matter physics

摘要: We present a new simple self-consistent field theory of polarizable flexible polymer chain under an external constant electric with account for the many-body electrostatic dipole correlations. show effects correlations on electric-field-induced globule-coil transition. demonstrate that only when is in coil conformation, monomers can be considered as pairwise. However, collapsed state, have to at level.

参考文章(26)
Rudolf Podgornik, Bing-Sui Lu, Ali Naji, Molecular recognition by van der Waals interaction between polymers with sequence-specific polarizabilities Journal of Chemical Physics. ,vol. 142, pp. 214904- ,(2015) , 10.1063/1.4921892
Francisco J. Solis, Monica Olvera de la Cruz, Collapse of flexible polyelectrolytes in multivalent salt solutions Journal of Chemical Physics. ,vol. 112, pp. 2030- 2035 ,(2000) , 10.1063/1.480763
L. D. Landau, J. S. Bell, J. B. Sykes, E. H. Dill, E. M. Lifshitz, Electrodynamics of continuous media ,(1960)
N. V. Brilliantov, D. V. Kuznetsov, R. Klein, Chain Collapse and Counterion Condensation in Dilute Polyelectrolyte Solutions Physical Review Letters. ,vol. 81, pp. 1433- 1436 ,(1998) , 10.1103/PHYSREVLETT.81.1433
H. Schiessel, P. Pincus, Counterion-Condensation-Induced Collapse of Highly Charged Polyelectrolytes Macromolecules. ,vol. 31, pp. 7953- 7959 ,(1998) , 10.1021/MA980823X
Rudolf Podgornik, David S. Dean, Ordering of anisotropic polarizable polymer chains on the full many-body level Journal of Chemical Physics. ,vol. 136, pp. 154905- 154905 ,(2012) , 10.1063/1.3703762
Marshall Fixman, Radius of Gyration of Polymer Chains The Journal of Chemical Physics. ,vol. 36, pp. 306- 310 ,(1962) , 10.1063/1.1732501