Examples for electronic and structural dynamics from mössbauer spectroscopy

作者: F. J. Litterst

DOI: 10.1007/BF02354749

关键词: JumpElectron hoppingAtmospheric temperature rangeMössbauer spectroscopyValence (chemistry)Analytical chemistryChemistryElectric field gradientCondensed matter physicsIron doped

摘要: Experimental examples are given which allow the application of stochastic jump models. Electron hopping in mixed valence minerals leads to electric field gradient and isomer shift fluctuations can be monitored over a wide temperature range. Correlated motion demonstrated occur iron doped β-NbH0.78 for FeMo6S8.

参考文章(37)
John B. Goodenough, The Verwey Transition Revisited Springer Netherlands. pp. 413- 425 ,(1980) , 10.1007/978-94-009-9076-0_14
F. Parak, E.W. Knapp, D. Kucheida, Protein dynamics Journal of Molecular Biology. ,vol. 161, pp. 177- 194 ,(1982) , 10.1016/0022-2836(82)90285-6
W. Petry, G. Vogl, Mössbauer study of localized diffusion in an interstitial cage European Physical Journal B. ,vol. 45, pp. 207- 213 ,(1982) , 10.1007/BF01302981
J. M. D. Coey, Mössbauer Spectroscopy of Silicate Minerals Springer, Boston, MA. pp. 443- 509 ,(1984) , 10.1007/978-1-4899-0462-1_14
E. W. Knapp, S. F. Fischer, F. Parak, The influence of protein dynamics on Mössbauer spectra Journal of Chemical Physics. ,vol. 78, pp. 4701- 4711 ,(1983) , 10.1063/1.445316
I U Heilmann, N B Olsen, J Staun Olsen, Electron Hopping and Temperature Dependent Oxidation States of Iron in Ilvaite Studied by Mössbauer Effect Physica Scripta. ,vol. 15, pp. 285- 288 ,(1977) , 10.1088/0031-8949/15/4/011
W R McKinnon, C M Hurd, I Shiozaki, On the conductivity of magnetite below the Verwey transition Journal of Physics C: Solid State Physics. ,vol. 14, ,(1981) , 10.1088/0022-3719/14/29/003
J.M.D. Coey, A. Moukarika, C.M. McDonagh, Electron hopping in cronstedtite Solid State Communications. ,vol. 41, pp. 797- 800 ,(1982) , 10.1016/0038-1098(82)91251-0