p-type doping with N and Li acceptors of ZnS grown by metalorganic vapor phase epitaxy

作者: L. Svob , C. Thiandoume , A. Lusson , M. Bouanani , Y. Marfaing

DOI: 10.1063/1.126139

关键词: Metalorganic vapour phase epitaxyMaterials scienceInorganic chemistryChemical vapor depositionEpitaxyLithiumPhotoluminescenceDopingSemiconductorConductivity

摘要: ZnS layers were grown by metalorganic vapor phase epitaxy on GaAs substrates using diethylzinc, ditertiarybutyl sulphide, and triallylamine as organometallic sources. After postgrowth rapid thermal annealing, the showed p-type conductivity with hole concentrations up to 1018 cm−3. Photoluminescence measurements gave additional indications of presence electrically active nitrogen acceptors. In separate experiments, lithium was diffused from a LiH solid source into without precursor. High-conductivity material directly obtained no need anneal.

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