Mechanical properties and morphology of microparticle and nanoparticle-filled polypropylene composites

作者: Rui-Juan Zhou , Thomas Burkhart

DOI: 10.1007/S10853-010-4304-Z

关键词: Izod impact strength testYoung's modulusYield (engineering)Charpy impact testUltimate tensile strengthMaterials scienceMicroparticleNanoparticleComposite materialComposite number

摘要: Hydrophilic microparticle and nanoparticle-filled isotactic polypropylene (iPP) composites containing 5 wt% particles were extruded in a Berstorff extruder then injection molded. For characterization the tensile unnotched Charpy impact tests performed. The results show that significant improvements strength, yield elongation, strength are achieved iPP/nanoparticle composite based on good dispersion quality of nanoparticles. In case iPP/microparticle composite, modulus markedly increased compared to neat matrix, but elongation drastically decreased due broad size distribution microparticles. fracture mechanisms discussed by studying surface morphology failed samples. Furthermore, influence crystalline behavior mechanical properties iPP was discussed.

参考文章(24)
Klaus Friedrich, Crazes and shear bands in semi-crystalline thermoplastics Springer Berlin Heidelberg. pp. 225- 274 ,(1983) , 10.1007/BFB0024059
Gang Wang, Xiao Yuan Chen, Rui Huang, Ling Zhang, Nano-CaCO3/polypropylene composites made with ultra-high-speed mixer Journal of Materials Science Letters. ,vol. 21, pp. 985- 986 ,(2002) , 10.1023/A:1016044204168
Robert F. Landel, Lawrence E. Nielsen, Mechanical Properties of Polymers and Composites ,(1993)
Yong Lin, Haibin Chen, Chi-Ming Chan, Jingshen Wu, High Impact Toughness Polypropylene/CaCO3 Nanocomposites and the Toughening Mechanism Macromolecules. ,vol. 41, pp. 9204- 9213 ,(2008) , 10.1021/MA801095D
WE van Zyl, M Monserrat Garcia, SH Sachin Jain, AU Sarkissov, Bag Bernard Schrauwen, G van Vliet, BA Boukamp, Polypropylene/SiO2 nanocomposites with improved mechanical properties Reviews on Advanced Materials Science. ,vol. 6, pp. 169- 175 ,(2005)
J. I. Velasco, J. A. De Saja, A. B. Martínez, FRACTURE BEHAVIOUR OF UNTREATED AND SILANE‐TREATED TALC‐FILLED POLYPROPYLENE COMPOSITES Fatigue & Fracture of Engineering Materials & Structures. ,vol. 20, pp. 659- 670 ,(1997) , 10.1111/J.1460-2695.1997.TB00299.X
Li Huang, Renbo Zhan, Yafei Lu, Mechanical Properties and Crystallization Behavior of Polypropylene/Nano-SiO2 Composites Journal of Reinforced Plastics and Composites. ,vol. 25, pp. 1001- 1012 ,(2006) , 10.1177/0731684406065131
Seon Hoon Ahn, Seong Hun Kim, Seung Goo Lee, Surface‐modified silica nanoparticle–reinforced poly(ethylene 2,6‐naphthalate) Journal of Applied Polymer Science. ,vol. 94, pp. 812- 818 ,(2004) , 10.1002/APP.21007