Electrical and optical properties of WO3 thin films

作者: M. Regragui , V. Jousseaume , M. Addou , A. Outzourhit , J.C. Bernéde

DOI: 10.1016/S0040-6090(01)01405-5

关键词: Electrical resistivity and conductivityOpticsThermionic emissionHall effectCondensed matter physicsThin filmDegenerate semiconductorDrude modelGrain boundaryChemistryConductivity

摘要: Tungsten trioxide (WO3) thin films were prepared by spray pyrolysis. The optical and electrical properties of intensively colored films were studied. It was found that the near-infrared reflectivity increases in the colored state. This behavior is typical of degenerate semiconducting materials. However, the variations of the electrical conductivity with the temperature for these films, indicates semiconducting behavior, while the carrier concentration (n), measured by the Hall effect, is typical of degenerate material. The optical …

参考文章(18)
John C. C. Fan, Frank J. Bachner, Properties of Sn‐Doped In2 O 3 Films Prepared by RF Sputtering Journal of The Electrochemical Society. ,vol. 122, pp. 1719- 1725 ,(1975) , 10.1149/1.2134117
K.F. Huang, T.M. Uen, Y.S. Gou, C.R. Huang, H.C. Yang, Temperature dependence of transport properties of evaporated indium tin oxide films Thin Solid Films. ,vol. 148, pp. 7- 15 ,(1987) , 10.1016/0040-6090(87)90116-7
M. V. Garcia‐Cuenca, J. L. Morenza, J. Esteve, Electron tunneling in heavily In‐doped polycrystalline CdS films Journal of Applied Physics. ,vol. 56, pp. 1738- 1743 ,(1984) , 10.1063/1.334170
R.B. Goldner, R.L. Chapman, G. Foley, E.L. Goldner, T. Haas, P. Norton, G. Seward, K.K. Wong, Recent research related to the development of electrochromic windows Solar Energy Materials. ,vol. 14, pp. 195- 203 ,(1986) , 10.1016/0165-1633(86)90046-8
V. Wittwer, O.F. Schirmer, P. Schlotter, Disorder dependence and optical detection of the Anderson transition in amorphous HxWO3 bronzes Solid State Communications. ,vol. 25, pp. 977- 980 ,(1978) , 10.1016/0038-1098(78)90887-6
Z. M. Jarzebski, Preparation and physical properties of transparent conducting oxide films physica status solidi (a). ,vol. 71, pp. 13- 41 ,(1982) , 10.1002/PSSA.2210710102
H.L. Ma, D.H. Zhang, P. Ma, S.Z. Win, S.Y. Li, Preparation and properties of transparent conducting indium tin oxide films deposited by reactive evaporation Thin Solid Films. ,vol. 263, pp. 105- 110 ,(1995) , 10.1016/0040-6090(95)06554-7
M Regragui, M Addou, A Outzourhit, J.C Bernéde, Elb El Idrissi, E Benseddik, A Kachouane, Preparation and characterization of pyrolytic spray deposited electrochromic tungsten trioxide films Thin Solid Films. ,vol. 358, pp. 40- 45 ,(2000) , 10.1016/S0040-6090(99)00682-3
R. L. Weiher, Electrical Properties of Single Crystals of Indium Oxide Journal of Applied Physics. ,vol. 33, pp. 2834- 2839 ,(1962) , 10.1063/1.1702560
C. W. Chen, T. K. Gustafson, Characteristics of an avalanche phototransistor fabricated on a Si surface Applied Physics Letters. ,vol. 39, pp. 161- 163 ,(1981) , 10.1063/1.92647