Chemistry of polynuclear transition-metal complexes in ionic liquids

摘要: Transition-metal chemistry in ionic liquids (IL) has achieved intrinsic fascination the last few years. The use of an IL as environmental friendly solvent, offers many advantages over traditional materials synthesis methods. change from molecular to reaction media leads new types being accessible. Room-temperature have been found be excellent for stabilising transition-metal clusters solution and crystallise homo- heteronuclear complexes clusters. Furthermore, solvent provides option replace high-temperature routes, such crystallisation melt or gas-phase deposition, by convenient room- low-temperature syntheses. Inorganic composed alkali metal cations polynuclear cluster anions are also known. Each these areas will discussed briefly this contribution.