Studies on Synthesis and Electrical Properties of CdS-Polyaniline Nanocomposite via Oxidation Polymerization
作者： Kose T D , Ramteke S P
DOI: 10.5923/J.CMATERIALS.20120204.01
关键词: Polyaniline nanofibers 、 Polyaniline 、 Nanoparticle 、 Cadmium sulfide 、 Polymerization 、 Materials science 、 Composite material 、 Polymer chemistry 、 Nanocomposite 、 Aniline 、 Intercalation (chemistry) 、 Chemical engineering
摘要: Nanocomposites of conducting polyaniline with CdS nanoparticles have been synthesized via in situ by o xi- dizing the complex aniline cad miu m sulfate at 3.5 p H. The effect CdS-nanoparticles on electrical conductivity was discussed. as prepared products were characterized FT-IR and Transmission electron Microscopy. FTIR absorption band 3600 - 3500 cm -1 confirmed highly attached nanoparticles. TEM showed part icles are spherical average diameter 19 n which evenly distributed poly mer matrix. uniform intercalation results a cooperative phenomenon between nanoparti- cles, consequence, increased nanocomposite to 6.50x10 -2 S/cm co mpared pure (10 -10 S/cm); Germaniu S/cm) Silicon -4 semiconductors. Its found be analogous existing semiconducting metals. fact is supported ample experimental characterizat ion evidences.
sapub.org参考文章(18)
ET Kang, KG Neoh, KL Tan, POLYANILINE: A POLYMER WITH MANY INTERESTING INTRINSIC REDOX STATES Progress in Polymer Science. ,vol. 23, pp. 277- 324 ,(1998) , 10.1016/S0079-6700(97)00030-0
Wei-Kang Lu, Ronald L. Elsenbaumer, Bernhard Wessling, Corrosion protection of mild steel by coatings containing polyaniline Synthetic Metals. ,vol. 71, pp. 2163- 2166 ,(1995) , 10.1016/0379-6779(94)03204-J
E.M. Geniès, A. Boyle, M. Lapkowski, C. Tsintavis, Polyaniline: A historical survey Synthetic Metals. ,vol. 36, pp. 139- 182 ,(1990) , 10.1016/0379-6779(90)90050-U
Yong Cao, Paul Smith, Alan J. Heeger, Counter-ion induced processibility of conducting polyaniline and of conducting polyblends of polyaniline in bulk polymers Synthetic Metals. ,vol. 48, pp. 91- 97 ,(1992) , 10.1016/0379-6779(92)90053-L
Sambhu Bhadra, Dipak Khastgir, Nikhil K Singha, Joong Hee Lee, None, PROGRESS IN PREPARATION, PROCESSING AND APPLICATIONS OF POLYANILINE Progress in Polymer Science. ,vol. 34, pp. 783- 810 ,(2009) , 10.1016/J.PROGPOLYMSCI.2009.04.003
Dominique Debarnot, Tiphaine Mérian, Fabienne Poncin-Epaillard, Film Chemistry Control and Growth Kinetics of Pulsed Plasma-Polymerized Aniline Plasma Chemistry and Plasma Processing. ,vol. 31, pp. 217- 231 ,(2011) , 10.1007/S11090-010-9271-2
Hongtao Liu, Danming Chao, Xincai Liu, Xiaoteng Jia, Libing He, Lili Cui, Lei Yao, Ce Wang, Design, synthesis and characterization of a novel self‐doped polyaniline derivative Polymer International. ,vol. 60, pp. 725- 729 ,(2011) , 10.1002/PI.2990
Shiro Kobayashi, Akira Makino, Enzymatic polymer synthesis: an opportunity for green polymer chemistry. Chemical Reviews. ,vol. 109, pp. 5288- 5353 ,(2009) , 10.1021/CR900165Z
Y. Wang, N. Herron, Photoconductivity of CdS nanocluster-doped polymers Chemical Physics Letters. ,vol. 200, pp. 71- 75 ,(1992) , 10.1016/0009-2614(92)87047-S
Dmitri Yu. Godovsky, Andrei E. Varfolomeev, David F. Zaretsky, R. L. Nayana Chandrakanthi, Andreas Kündig, Christoph Weder, Walter Caseri, Preparation of nanocomposites of polyaniline and inorganic semiconductors Journal of Materials Chemistry. ,vol. 11, pp. 2465- 2469 ,(2001) , 10.1039/B103048P