Two band transport and disorder effects in a series of organic alloys: (TTF1-xTSeFx)-TCNQ (tetrathiafulvalene-tetraselenafulvalene-tetracyanoquinodimethane)

作者: P.M. Chaikin , J.F. Kwak , R.L. Greene , S. Etemad , E.M. Engler

DOI: 10.1016/0038-1098(76)90819-X

关键词: IonPhysical chemistryTetracyanoquinodimethaneSeebeck coefficientChain (algebraic topology)TetrathiafulvaleneSeries (mathematics)ConductivityCondensed matter physicsChemistrySolid solution

摘要: Abstract We have measured the thermoelectric power of organic solid solutions (TTF1-xTSeFx)-TCNQ from 300 to 20 K. find that in TTF- TCNQ conductivity is dominated by chain down 58 K and TTF dominates between 38 In TSeF-TCNQ cation anion conductivities are comparable at all temperatures. also disorder leads band tailing a finite density localized states within Peierls gap.

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