Laser Doping and Recrystallization for Amorphous Silicon Films by Plasma-Enhanced Chemical Vapor Deposition

作者: Dong Sing Wuu , Shui Yang Lien , Jui Hao Wang , Hsin-Yuan Mao , In-Cha Hsieh

DOI: 10.4028/WWW.SCIENTIFIC.NET/MSF.475-479.3791

关键词: Inorganic chemistryCrystalline siliconAmorphous siliconMonocrystalline siliconMaterials scienceDopingNanocrystalline siliconOptoelectronicsDopantPlasma-enhanced chemical vapor depositionPolycrystalline silicon

摘要: One of the most challenging problems to develop polycrystalline silicon thin-film solar cells is growth crystalline on foreign, low-cost and low-temperature substrates. In this paper, a laser doping technique was developed for plasma-deposited amorphous film. A process combination recrystallization dopant diffusion (phosphorous or boron) achieved simultaneously by annealing process. The precursor synthesized sol-gel method spin-coated sample. After irradiation, grain size doped examined be about 0.5~1.0 µm. concentrations 2×1019 5× 1018 cm-3 with Hall mobilities 92.6 37.5 cm²/V-s were laser-diffused phosphorous- boron-type polysilicon films, respectively.

参考文章(10)
M. S. Haque, H. A. Naseem, W. D. Brown, Aluminum‐induced crystallization and counter‐doping of phosphorous‐doped hydrogenated amorphous silicon at low temperatures Journal of Applied Physics. ,vol. 79, pp. 7529- 7536 ,(1996) , 10.1063/1.362425
Seiichiro Higashi, Kentaro Ozaki, Keiji Sakamoto, Yoshiaki Kano, Toshiyuki Sameshima, Electrical Properties of Excimer-Laser-Crystallized Lightly Doped Polycrystalline Silicon Films Japanese Journal of Applied Physics. ,vol. 38, pp. L857- L860 ,(1999) , 10.1143/JJAP.38.L857
Shuich Fujii, Yuko Fukawa, Hiroaki Takahashi, Yosuke Inomata, Kenichi Okada, Kenji Fukui, Katsuhiko Shirasawa, Production technology of large-area multicrystalline silicon solar cells Solar Energy Materials and Solar Cells. ,vol. 65, pp. 269- 275 ,(2001) , 10.1016/S0927-0248(00)00102-1
Kuninori Kitahara, Katsuyuki Suga, Akito Hara, Kazuo Nakajima, Phase Variation of Amorphous-Si and Poly-Si Thin Films with Excimer Laser Irradiation Japanese Journal of Applied Physics. ,vol. 35, ,(1996) , 10.1143/JJAP.35.L1473
M Cuscunà, A Bonfiglietti, R Carluccio, L Mariucci, F Mecarini, A Pecora, M Stanizzi, A Valletta, G Fortunato, A novel fabrication process for polysilicon thin film transistors with source/drain contacts formed by deposition and lift-off of highly doped layers Solid-state Electronics. ,vol. 46, pp. 1351- 1358 ,(2002) , 10.1016/S0038-1101(02)00082-5
Kuninori Kitahara, Akihiro Moritani, Akito Hara, Masahiro Okabe, Micro-Scale Characterization of Crystalline Phase and Stress in Laser-Crystallized Poly-Si Thin Films by Raman Spectroscopy. Japanese Journal of Applied Physics. ,vol. 38, ,(1999) , 10.1143/JJAP.38.L1312
R.B. Bergmann, G. Oswald, M. Albrecht, V. Gross, Solid-phase crystallized Si films on glass substrates for thin film solar cells Solar Energy Materials and Solar Cells. ,vol. 46, pp. 147- 155 ,(1997) , 10.1016/S0927-0248(97)00006-8
Toshiki Kaneko, Ken-ichi Onisawa, Masatoshi Wakagi, Yoshiaki Kita, Tetsuroh Minemura, Crystalline fraction of microcrystalline silicon films prepared by plasma-enhanced chemical vapor deposition using pulsed silane flow Japanese Journal of Applied Physics. ,vol. 32, pp. 4907- 4911 ,(1993) , 10.1143/JJAP.32.4907
H. Tomita, M. Negishi, T. Sameshima, S. Usui, Submicrometer poly-Si CMOS fabrication with low-temperature laser doping IEEE Electron Device Letters. ,vol. 10, pp. 547- 549 ,(1989) , 10.1109/55.43135