Generation of functionally substituted vinyllithium compounds - results and calculations☆

作者: Richard R. Schmidt , Jörg Talbiersky , Peter Russegger

DOI: 10.1016/S0040-4039(01)86564-3

关键词: Acrylic acidOrganic chemistryChemistryAb initioRegioselectivity

摘要: Abstract Highly regioselective lithiation of β-functionally substituted acrylic acid derivatives was observed under various conditions. Theoretical investigations with the aid ab initio and semi-empirical methods were carried out to explain experimental result.

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