The course and mechanism of autoxidation reactions in olefinic and polyolefinic substances, including rubber

摘要: Abstract The tendency of olefins to absorb molecular oxygen increases rapidly with increase in unsaturation. In monoolefins absorption is usually very slow unless it actively promoted by irradiation, the use temperatures above room-temperature, or chemical catalysts; dienes and trienes becomes considerable diffused daylight; higher polyenes tends occur unpreventibly excessively. strong towards oxidation shown appears be shared unconjugated conjugated substances alike, although precise courses reaction are probably somewhat different two cases. present paper attention focussed mainly on monoolefinic polyolefinic substances.