Structural and mechanical aspects of interaction of polymers with low-molecular-mass substances

摘要: Abstract Specific features of complexation between low-moiecular-mass compounds (LMs) and polymers were discussed in terms structural inhomogeneity amorphous glassy polymers. Introduction LMs into the was shown to be associated with distribution two different forms, which are characterized by energetics bonding polymer matrix. This factor responsible for a complicated character molecular dynamics polymer/LM system mechanical behavior such complex materials whole. The cases, when macroscopic containing LM primarily controlled form, this compound existed matrix, considered. future development direction modification possibilities its practical application improvement response outlined.