Novel Labile Protected Amine Terpolymers for the Preparation of Patterned Functionalized Surfaces: Synthesis and Characterization

作者: Felix Braun , Lukas Eng , Sven Trogisch , Brigitte Voit

DOI: 10.1002/MACP.200350015

关键词: MethacrylamideCovalent bondAmine gas treatingCopolymerChemistryNitroProtecting groupRadical polymerizationMonomerPolymer chemistry

摘要: Photolabile terpolymers have been designed and used to prepare thin organic films covalently attached glass silicon substrates. For this, containing photolabile protected amine functions introduced by N-(N-nitroveratryloxycarbonylaminopropyl)methacrylamide as well (trimethoxysilyl)propylmethacrylate MMA comonomers synthesized via free radical polymerization. The nitro group protecting leads a retardation of the But complete removal non-reacted monomer from reaction product without gelation anchoring groups was achieved. these were structured imagewise UV laser light irradiation in order create defined functional areas at template surface ready for further modification attachment nanoobjects. selective deprotection verified UV-imaging using fluorescence labeling.

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