Comparison of Enantioselective CEC Separation of OT-MIP Capillary Columns with Templates of Various Camphor Derivatives Made by the Pre-established General Preparation Protocol
作者： Shabi Abbas Zaidi , Seung-Mi Lee , Ju-Young Lee , Won-Jo Cheong
DOI: 10.5012/BKCS.2010.31.10.2934
关键词: Enantioselective synthesis 、 Hydrazone 、 Chromatography 、 Column chromatography 、 Chemistry 、 Template 、 Molecule 、 Capillary action 、 Enantiomer 、 Polymer
摘要: Some open tubular (OT) molecule imprinted polymer (MIP) silica capillary columns with templates of camphor derivatives such as 10-camphorsulfonic acid (10-CSA), 10-camphorsulfonamide (10-CS) and camphor-p-tosyl hydrazone (CTH) have been successfully prepared by the prior generalized preparation protocol. The three MIP thin layers different showed quite morphologies. chiral selectivity each column for template enantiomers was optimized changing eluent composition pH. optimization conditions were found to be MIPs. This work suggests prospective successful extension protocol OT-MIP toward a variety chemical groups.
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