Direct Experimental Evidence of Halide Ionic Migration under Bias in CH3NH3PbI3–xClx-Based Perovskite Solar Cells Using GD-OES Analysis
作者： Heejae Lee , Sofia Gaiaschi , Patrick Chapon , Arthur Marronnier , Heeryung Lee
DOI: 10.1021/ACSENERGYLETT.7B00150
关键词: Ion 、 Hysteresis 、 Chemical physics 、 Inorganic chemistry 、 Ionic bonding 、 Glow discharge 、 Halide 、 Perovskite (structure) 、 Chemistry 、 Crystal growth 、 Polarization (electrochemistry)
摘要: … ionic migration of halogen components (I – and Cl – ) of a CH 3 NH 3 PbI 3–x Cl x perovskite film under an applied bias … Furthermore, no migration of lead and nitrogen ions is observed …
archives-ouvertes.fr
figshare.com
acs.org
sci-hub.se 参考文章(36)
Christopher Eames, Jarvist M Frost, Piers RF Barnes, Brian C O’regan, Aron Walsh, M Saiful Islam, None, Ionic transport in hybrid lead iodide perovskite solar cells Nature Communications. ,vol. 6, pp. 7497- 7497 ,(2015) , 10.1038/NCOMMS8497
Filippo De Angelis, Jon M. Azpiroz, Edoardo Mosconi, Juan Bisquert, Defect migration in methylammonium lead iodide and its role in perovskite solar cell operation Energy and Environmental Science. ,vol. 8, pp. 2118- 2127 ,(2015) , 10.1039/C5EE01265A
Martin A. Green, Anita Ho-Baillie, Henry J. Snaith, The emergence of perovskite solar cells Nature Photonics. ,vol. 8, pp. 506- 514 ,(2014) , 10.1038/NPHOTON.2014.134
Jorge Pisonero, Beatriz Fernández, Rosario Pereiro, Nerea Bordel, Alfredo Sanz-Medel, Glow-discharge spectrometry for direct analysis of thin and ultra-thin solid films Trends in Analytical Chemistry. ,vol. 25, pp. 11- 18 ,(2006) , 10.1016/J.TRAC.2005.04.019
Jing Wei, Yicheng Zhao, Heng Li, Guobao Li, Jinlong Pan, Dongsheng Xu, Qing Zhao, Dapeng Yu, Hysteresis Analysis Based on the Ferroelectric Effect in Hybrid Perovskite Solar Cells Journal of Physical Chemistry Letters. ,vol. 5, pp. 3937- 3945 ,(2014) , 10.1021/JZ502111U
Dimitri Mercier, Muriel Bouttemy, Jackie Vigneron, Patrick Chapon, Arnaud Etcheberry, GD-OES and XPS coupling: A new way for the chemical profiling of photovoltaic absorbers Applied Surface Science. ,vol. 347, pp. 799- 807 ,(2015) , 10.1016/J.APSUSC.2015.04.093
E. L. Unger, E. T. Hoke, C. D. Bailie, W. H. Nguyen, A. R. Bowring, T. Heumüller, M. G. Christoforo, M. D. McGehee, Hysteresis and transient behavior in current–voltage measurements of hybrid-perovskite absorber solar cells Energy and Environmental Science. ,vol. 7, pp. 3690- 3698 ,(2014) , 10.1039/C4EE02465F
Pascal Sánchez, Beatriz Fernández, Armando Menéndez, Rosario Pereiro, Alfredo Sanz-Medel, Pulsed radiofrequency glow discharge optical emission spectrometry for the direct characterisation of photovoltaic thin film silicon solar cells Journal of Analytical Atomic Spectrometry. ,vol. 25, pp. 370- 377 ,(2010) , 10.1039/B923884K
Michael R. Winchester, Richard Payling, Radio-frequency glow discharge spectrometry:. A critical review Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 59, pp. 607- 666 ,(2004) , 10.1016/J.SAB.2004.02.013
Akihiro Kojima, Kenjiro Teshima, Yasuo Shirai, Tsutomu Miyasaka, Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells Journal of the American Chemical Society. ,vol. 131, pp. 6050- 6051 ,(2009) , 10.1021/JA809598R