Determination and Degradation of Potassium Bromate Content in Dough and Bread Samples Due to the Presence of Metals

作者: Ahmad Abu-Obaid , Shatha AbuHasan , Basem Shraydeh

DOI: 10.4236/AJAC.2016.76046

关键词: CatalysisBromateInductively coupled plasma mass spectrometryAbsorbanceIodidePotassium bromateIodineChemistryInorganic chemistryDegradation (geology)

摘要: Potassium bromate (PB) is used in bread making as an agent of maturation; however, it is classified as a potential carcinogen. In the present study, a rapid, simple, precise and accurate testing method has been developed to determine level bromate ions bread, which based on reaction ions with iodide in acidic medium produce iodine (I2). The absorbance (I2) was measured at 352 nm, and reacted during first 3 minutes after initiation reaction. proposed been successfully applied determination commercial bread. In this work, we found that alone degraded about 400°C, however, they 150°C - 200°C, mightbe due to presence metals [Fe, Mg, Zn, Mn, Cu Al] flour served as catalysts. study use two grams (2 g) PB per bag flour (60 kg) was safe.

参考文章(12)
A. Benmoussa, J. Lamsaouri, A. Zahidi, M. Ansar, J. Taoufik, J. El-Harti, M. O. B. Idrissi, M. Draoui, Y. Rahali, H. Benziane, A simple and rapid method for spectrophotometric determination of bromate in bread Electronic journal of environmental, agricultural and food chemistry. ,vol. 10, pp. 1803- 1808 ,(2011)
Martha M. Moore, Tao Chen, Mutagenicity of bromate: Implications for cancer risk assessment Toxicology. ,vol. 221, pp. 190- 196 ,(2006) , 10.1016/J.TOX.2005.12.018
EO Ojeka, MC Obidiaku, C Enukorah, Spectrophotometeric determination of bromate in bread by the oxidation of dyes Journal of Applied Sciences and Environmental Management. ,vol. 10, pp. 43- 46 ,(2006) , 10.4314/JASEM.V10I3.17318
Li Zhang, Weijun Zhou, Dong-Hui Li, A descent modified Polak–Ribière–Polyak conjugate gradient method and its global convergence Ima Journal of Numerical Analysis. ,vol. 26, pp. 629- 640 ,(2006) , 10.1093/IMANUM/DRL016
Kathleen C.M. Campbell, Bromate-induced ototoxicity. Toxicology. ,vol. 221, pp. 205- 211 ,(2006) , 10.1016/J.TOX.2005.12.015
S. Gandikota, F. MacRitchie, Expansion capacity of doughs: methodology and applications Journal of Cereal Science. ,vol. 42, pp. 157- 163 ,(2005) , 10.1016/J.JCS.2005.02.007
K.M. Crofton, Bromate: concern for developmental neurotoxicity? Toxicology. ,vol. 221, pp. 212- 216 ,(2006) , 10.1016/J.TOX.2006.01.021
Keswara Rao Vadlamani, Paul A. Seib, Effect of Zinc and Aluminum Ions in Breadmaking Cereal Chemistry. ,vol. 76, pp. 355- 360 ,(1999) , 10.1094/CCHEM.1999.76.3.355
JAO Oyekunle, AS Adekunle, AO Ogunfowokan, GO Olutona, OB Omolere, None, Bromate and trace metal levels in bread loaves from outlets within Ile-Ife Metropolis, Southwestern Nigeria Toxicology reports. ,vol. 1, pp. 224- 230 ,(2014) , 10.1016/J.TOXREP.2014.05.007