Synthesis and characterization of two novel [Ru(bpy)(2)(phen)](2+)-based electrochemiluminescent labels
作者： Peng Wang , Guoyi Zhu
DOI: 10.1002/1522-7243(200007/08)15:4<261::AID-BIO595>3.0.CO;2-L
关键词: Bipyridine 、 Crystallography 、 Cyclic voltammetry 、 Photochemistry 、 Photoluminescence 、 Electrochemiluminescence 、 Hexafluorophosphate 、 Electrochemistry 、 Chemistry 、 Ruthenium
摘要: Two novel electrochemiluminescent labels, bis(2,2'-bipyridine)[5-(3-carboxylic acid-propionamido)1,10-phenanthroline]ruthenium(II) hexafluorophosphate dihydrate and bis(2,2'-bipyridine)[5-(4-carboxylic acid-butanamido)-1,10-phenanthroline]ruthenium(II) dihydrate, were synthesized confirmed by IRelemental analysis, H-1-NMR spectra completely assigned using the (HH)-H-1-H-1 COSY technique. Cyclic voltammograms with different scan rates showed quasireversible electrochemical behaviour of two Ru (II) complex labels in MeCN solution. Electronic absorption, photoluminescence electrochemiluminescence Ru(II) complexes also characterized. Copyright (C) 2000 John Wiley & Sons, Ltd.
sci-hub.se 参考文章(20)
J H Kenten, S Gudibande, J Link, J J Willey, B Curfman, E O Major, R J Massey, Improved electrochemiluminescent label for DNA probe assays: rapid quantitative assays of HIV-1 polymerase chain reaction products. Clinical Chemistry. ,vol. 38, pp. 873- 879 ,(1992) , 10.1093/CLINCHEM/38.6.873
Naoyoshi EGASHIRA, Yasushi NABEYAMA, Yoshiaki KURAUCHI, Kazuya OHGA, Electrochemiluminescence of Hydroxyl Compounds by Cyclic Square-Wave Electrolysis and Its Application to an Alcohol Sensor Analytical Sciences. ,vol. 12, pp. 793- 795 ,(1996) , 10.2116/ANALSCI.12.793
Michael J. Cook, Anthony P. Lewis, Glenn S. G. McAuliffe, Vladimir Skarda, Andrew J. Thomson, John L. Glasper, David J. Robbins, Luminescent metal complexes. Part 1. Tris-chelates of substituted 2,2′-bipyridyls with ruthenium (II) as dyes for luminescent solar collectors Journal of The Chemical Society-perkin Transactions 1. ,vol. 15, pp. 1293- 1301 ,(1984) , 10.1039/P29840001293
Stefan Ruile, Oliver Kohle, Peter Péchy, Michael Grätzel, None, Novel sensitisers for photovoltaic cells. Structural variations of Ru(II) complexes containing 2,6-bis(1-methylbenzimidazol-2-yl)pyridine Inorganica Chimica Acta. ,vol. 261, pp. 129- 140 ,(1997) , 10.1016/S0020-1693(97)05457-1
André Gourdon, Jean-Pierre Launay, Mononuclear and Binuclear Tetrapyrido[2,3-a:3‘,2‘-c:2‘‘,3‘‘-h:3‘‘‘,2‘‘‘-j]phenazine (tphz) Ruthenium Complexes Inorganic Chemistry. ,vol. 37, pp. 5336- 5341 ,(1998) , 10.1021/IC980312R
Jaime Gonzales-Velasco, Israel Rubinstein, R. J. Crutchley, A. B. P. Lever, Allen J. Bard, Electrogenerated chemiluminescence. 42. Electrochemistry and electrogenerated chemiluminescence of the tris(2,2'-bipyrazine)ruthenium(II) system Inorganic Chemistry. ,vol. 14, pp. 822- 825 ,(1983) , 10.1021/IC00147A024
J-P. Lecomte, A. Kirsch-De Mesmaeker, M. Demeunynck, J. Lhomme, Synthesis and characterisation of a new DNA-binding bifunctional ruthenium(II) complex Journal of the Chemical Society, Faraday Transactions. ,vol. 89, pp. 3261- 3269 ,(1993) , 10.1039/FT9938903261
Ronald R. Ruminski, Sina Underwood, Kristen Vallely, Sandra J. Smith, Synthesis and Characterization of [Ru(dpop‘)2](PF6)2. A Ruthenium(II) Complex with the Novel Mixed-Denticity Bridging Ligand Dipyrido(2,3-a:3‘,2‘-j)phenazine (dpop‘) Inorganic Chemistry. ,vol. 37, pp. 6528- 6531 ,(1998) , 10.1021/IC980530K
A Knight, A review of recent trends in analytical applications of electrogenerated chemiluminescence Trends in Analytical Chemistry. ,vol. 18, pp. 47- 62 ,(1999) , 10.1016/S0165-9936(98)00086-7
John G. Bruno, Preliminary studies of the enhanced electrochemiluminescence of 2,3-diaminonaphthalene in the presence of specific metal ions Journal of Bioluminescence and Chemiluminescence. ,vol. 13, pp. 139- 145 ,(1998) , 10.1002/(SICI)1099-1271(199805/06)13:3<139::AID-BIO480>3.0.CO;2-F