Synchrotron X-ray radiography studies of pitting corrosion of stainless steel: extraction of pit propagation parameters

作者: Majid Ghahari , Donal Krouse , Nicholas Laycock , Trevor Rayment , Cristiano Padovani

DOI: 10.1016/J.CORSCI.2015.06.023

关键词: MetallurgyChloridePitting corrosionCurrent densitySynchrotronLayer (electronics)Materials scienceConductivityCorrosionAnode

摘要: Abstract In situ synchrotron X-ray radiography was used to observe the evolution of 2D pits growing at edge stainless steel foils in chloride solutions varying concentrations under current and potential control. A method developed for measuring local anodic density along perimeter from rate advance pit into metal. Pit depth tends increase with time kinetics consistent diffusion control (under a salt layer), whereas lateral development (on film-free surfaces) is influenced by solution conductivity. Perforated covers formed on their growth stability.

参考文章(56)
H. W. Pickering, R. P. Frankenthal, On the Mechanism of Localized Corrosion of Iron and Stainless Steel I . Electrochemical Studies Journal of The Electrochemical Society. ,vol. 119, pp. 1297- 1304 ,(1972) , 10.1149/1.2403982
Jakob Enerhaug, Unni M. Steinsmo, O̸ystein Grong, Leif Rune Hellevik, Dissolution and Repassivation Kinetics of a 12.3Cr-2.6Mo-6.5Ni Super Martensitic Stainless Steel A Comparative Study Journal of The Electrochemical Society. ,vol. 149, ,(2002) , 10.1149/1.1474429
N. J. Laycock, M. H. Moayed, R. C. Newman, Metastable Pitting and the Critical Pitting Temperature Journal of The Electrochemical Society. ,vol. 145, pp. 2622- 2628 ,(1998) , 10.1149/1.1838691
Unni Steinsmo, Hugh S. Isaacs, Dissolution and Repassivation Kinetics of Fe‐Cr Alloys in Pit Solutions I . Effect of the Surface Salt Layer Journal of The Electrochemical Society. ,vol. 140, pp. 643- 653 ,(1993) , 10.1149/1.2056137
A.C. West, R.-D. Grimm, D. Landolt, C. Deslouis, B. Tribollet, Electrohydrodynamic impedance study of anodically formed salt films on iron in chloride solutions Journal of Electroanalytical Chemistry. ,vol. 330, pp. 693- 706 ,(1992) , 10.1016/0022-0728(92)80337-4
J. W. Tester, H. S. Isaacs, Diffusional Effects in Simulated Localized Corrosion Journal of The Electrochemical Society. ,vol. 122, pp. 1438- 1445 ,(1975) , 10.1149/1.2134039
N.J. Laycock, R.C. Newman, Localised dissolution kinetics, salt films and pitting potentials Corrosion Science. ,vol. 39, pp. 1771- 1790 ,(1997) , 10.1016/S0010-938X(97)00049-8
G. S. Frankel, L. Stockert, F. Hunkeler, H. Boehni, Metastable Pitting of Stainless Steel Corrosion. ,vol. 43, pp. 429- 436 ,(1987) , 10.5006/1.3583880
N. J. Laycock, S. P. White, J. S. Noh, P. T. Wilson, R. C. Newman, Perforated Covers for Propagating Pits Journal of The Electrochemical Society. ,vol. 145, pp. 1101- 1108 ,(1998) , 10.1149/1.1838423