Band alignment between GeTe and SiO2/metals for characterization of junctions in nonvolatile resistance change elements

作者: EK Chua , LP Shi , MH Li , R Zhao , TC Chong

DOI: 10.1063/1.3599057

关键词: Work functionFermi levelHeterojunctionBand diagramAmorphous solidValence (chemistry)Condensed matter physicsCrystallographyX-ray photoelectron spectroscopyTungstenMaterials science

摘要: GeTe materials were characterized using x-ray photoelectron spectroscopy in both the amorphous and crystalline states. Valence conduction band alignments relative to a SiO2 reference measured allow diagram, work function, electron affinity be inferred. Hole barrier heights was also studied for several metal/GeTe systems (metal=Al,Ni,W) extract charge neutrality level of these interfaces Near perfect Fermi-level pinning observed contact with all metals much less GeTe.

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