Partition coefficients of quinones and hydroquinones and their relation to biochemical reactivity
作者： Peter R. Rich , Robert Harper
DOI: 10.1016/0014-5793(90)81139-F
关键词: Computational chemistry 、 Hydroquinone 、 Octanol 、 Partition coefficient 、 Quinone binding 、 Plastoquinone 、 Quinone 、 Redox 、 Stereochemistry 、 Cyclohexane 、 Chemistry 、 Biophysics 、 Genetics 、 Cell biology 、 Biochemistry 、 Molecular biology 、 Structural biology
摘要: Some major effects of ring substituents on the partition coefficients quinone headgroups are described. Attention is drawn to large differences in cyclohexane/water two freely diffusing redox forms, quinone, Q, and hydroquinone, QH2. Methoxy cause a marked increase coefficient but this effect absent also not seen measurements octanol/water. The relation between biochemical specificity binding sites explored.
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