Comprehensive Kinetic Screening of Catalysts Using Reaction Calorimetry

摘要: The protocol based on reaction calorimetry which is described in this paper offers a multidimensional kinetic and stability profile of catalyst candidate liquid multiphase reactions. scale-transparent picture properties provided by method should make it generally useful for rapid screening candidates catalytic process steps as well fundamental mechanistic studies organic In the example here, new Pd complexes with nitrogen-based ligands were found to be more active than phosphapalladacycles Heck coupling aryl halides olefins.