A cylindrical cavity with two different hydrogen-binding boundaries: the calix[4]arene skeleton screwed onto the meso-positions of the calix[4]pyrrole†
作者： Lucia Bonomo , Euro Solari , Gülsen Toraman , Rosario Scopelliti , Carlo Floriani
DOI: 10.1039/A907563A
关键词: Pyrrole 、 Crystallography 、 Chemistry 、 Hydrogen 、 Stereochemistry 、 Conformational isomerism 、 Condensation
摘要: The acid-catalyzed condensation of pyrrole with p- or m-hydroxyacetophenone led to the formation meso-tetramethyltetrakis(hydroxyphenyl)calix[4]pyrroles occurring in three isomeric forms, cone conformer displaying topologically variable multi-site multi-point surfaces for binding neutral anionic substrates.
rsc.org
poliba.it参考文章(15)
Leonard R. MacGillivray, Jerry L. Atwood, A chiral spherical molecular assembly held together by 60 hydrogen bonds Nature. ,vol. 389, pp. 469- 472 ,(1997) , 10.1038/38985
Jonathan L. Sessler, Andrei Andrievsky, Philip A. Gale, Vincent Lynch, Anion Binding: Self‐Assembly of Polypyrrolic Macrocycles Angewandte Chemie. ,vol. 35, pp. 2782- 2785 ,(1996) , 10.1002/ANIE.199627821
Philip A. Gale, John W. Genge, Vladimír Král, M.Anthony McKervey, Jonathan L. Sessler, Andrew Walker, First synthesis of an expanded calixpyrrole Tetrahedron Letters. ,vol. 38, pp. 8443- 8444 ,(1997) , 10.1016/S0040-4039(97)10275-1
Christoph A. Schalley, Ronald K. Castellano, Marcus S. Brody, Dmitry M. Rudkevich, Gary Siuzdak, Julius Rebek, Investigating Molecular Recognition by Mass Spectrometry: Characterization of Calixarene-Based Self-Assembling Capsule Hosts with Charged Guests Journal of the American Chemical Society. ,vol. 121, pp. 4568- 4579 ,(1999) , 10.1021/JA990276A
Garry S. Hanan, Dirk Volkmer, Ulrich S. Schubert, Jean-Marie Lehn, Gerhard Baum, Dieter Fenske, Coordination Arrays: Tetranuclear Cobalt(II) Complexes with [2 × 2]‐Grid Structure Angewandte Chemie. ,vol. 36, pp. 1842- 1844 ,(1997) , 10.1002/ANIE.199718421
Philip A. Gale, Jonathan L. Sessler, Vladimír Král, Vincent Lynch, Calix[4]pyrroles: Old Yet New Anion-Binding Agents Journal of the American Chemical Society. ,vol. 118, pp. 5140- 5141 ,(1996) , 10.1021/JA960307R
M. Morgan Conn, Julius Rebek, Self-Assembling Capsules Chemical Reviews. ,vol. 97, pp. 1647- 1668 ,(1997) , 10.1021/CR9603800
Philip A. Gale, Jonathan L. Sessler, Vincent Lynch, Petra I. Sansom, Synthesis of a new cylindrical calix[4]arene-calix[4]pyrrole pseudo dimer Tetrahedron Letters. ,vol. 37, pp. 7881- 7884 ,(1996) , 10.1016/0040-4039(96)01805-9
Irene Higler, Peter Timmerman, Willem Verboom, David N. Reinhoudt, Combination of calix[4]arenes and resorcin[4]arenes for the complexation of steroids Journal of Organic Chemistry. ,vol. 61, pp. 5920- 5931 ,(1996) , 10.1021/JO960256G
Katrina A. Jolliffe, Peter Timmerman, David N. Reinhoudt, Noncovalent Assembly of a Fifteen-Component Hydrogen-Bonded Nanostructure Angewandte Chemie International Edition. ,vol. 38, pp. 933- 937 ,(1999) , 10.1002/(SICI)1521-3773(19990401)38:7<933::AID-ANIE933>3.0.CO;2-3