Design and development of trivalent aluminum ions induced self-healing polyacrylic acid novel hydrogels
作者： Sadiya Anjum , Pramod Gurave , Manohar V. Badiger , Arun Torris , Neha Tiwari
DOI: 10.1016/J.POLYMER.2017.08.045
关键词: Ion 、 Rheology 、 Polymer chemistry 、 Swelling 、 Elongation 、 Self-healing hydrogels 、 Materials science 、 Ionic bonding 、 Polymer 、 Polyacrylic acid
摘要: Abstract Development of ionically crosslinked superabsorbent polyacrylic acid (PAA) self-healing hydrogels using trivalent aluminum ions was investigated. The PAA exhibited excellent behavior depending on the amount within matrix. migration these polymer matrix responsible for physical crosslinking hydrogel and origin ability. PAA-Al were insoluble in water significantly high degree swelling (∼4000%). Hydrogel also good mechanical properties with level elongation. Excellent efficiency observed under dynamic as well oscillatory rheological measurements. presence Al facilitated ability because ionic interaction gels which plays key role reversible sacrificial bonds reforms upon reversal deformative force.
sci-hub.se 参考文章(38)
Wen Jiang Zheng, Jie Gao, Zhao Wei, Jinxiong Zhou, Yong Mei Chen, None, Facile fabrication of self-healing carboxymethyl cellulose hydrogels European Polymer Journal. ,vol. 72, pp. 514- 522 ,(2015) , 10.1016/J.EURPOLYMJ.2015.06.013
Tianxin Miao, Spencer L Fenn, Patrick N Charron, Rachael A Floreani, Self-Healing and Thermoresponsive Dual-Cross-Linked Alginate Hydrogels Based on Supramolecular Inclusion Complexes Biomacromolecules. ,vol. 16, pp. 3740- 3750 ,(2015) , 10.1021/ACS.BIOMAC.5B00940
Hiroshi Yokoi, Eigo Nomoto, Shuji Ikoma, Reversible formation of iron(III) ion clusters in the poly(acrylic acid)–Fe3+complex gel with changes in the water content J. Mater. Chem.. ,vol. 3, pp. 389- 392 ,(1993) , 10.1039/JM9930300389
Esmaiel Jabbari, Samyra Nozari, None, Swelling behavior of acrylic acid hydrogels prepared by γ-radiation crosslinking of polyacrylic acid in aqueous solution European Polymer Journal. ,vol. 36, pp. 2685- 2692 ,(2000) , 10.1016/S0014-3057(00)00044-6
Jeannine E Elliott, Mara Macdonald, Jun Nie, Christopher N Bowman, None, Structure and swelling of poly(acrylic acid) hydrogels: effect of pH, ionic strength, and dilution on the crosslinked polymer structure Polymer. ,vol. 45, pp. 1503- 1510 ,(2004) , 10.1016/J.POLYMER.2003.12.040
Roberta Censi, Piera Di Martino, Tina Vermonden, Wim E. Hennink, Hydrogels for protein delivery in tissue engineering Journal of Controlled Release. ,vol. 161, pp. 680- 692 ,(2012) , 10.1016/J.JCONREL.2012.03.002
Deniz C Tuncaboylu, Murat Sari, Wilhelm Oppermann, Oguz Okay, None, Tough and Self-Healing Hydrogels Formed via Hydrophobic Interactions Macromolecules. ,vol. 44, pp. 4997- 5005 ,(2011) , 10.1021/MA200579V
Hoang D. Lu, Manoj B. Charati, Iris L. Kim, Jason A. Burdick, Injectable shear-thinning hydrogels engineered with a self-assembling Dock-and-Lock mechanism. Biomaterials. ,vol. 33, pp. 2145- 2153 ,(2012) , 10.1016/J.BIOMATERIALS.2011.11.076
A. Phadke, C. Zhang, B. Arman, C.-C. Hsu, R. A. Mashelkar, A. K. Lele, M. J. Tauber, G. Arya, S. Varghese, Rapid self-healing hydrogels. Proceedings of the National Academy of Sciences of the United States of America. ,vol. 109, pp. 4383- 4388 ,(2012) , 10.1073/PNAS.1201122109
Yinlei Lin, Guangji Li, An intermolecular quadruple hydrogen-bonding strategy to fabricate self-healing and highly deformable polyurethane hydrogels J. Mater. Chem. B. ,vol. 2, pp. 6878- 6885 ,(2014) , 10.1039/C4TB00862F