Time-Resolved X-Ray Studies of Crystallization and Melting in Poly(ARYL Ether Ether Ketone)
作者： BS Hsiao , KH Gardner , None
DOI: 10.1007/978-94-011-1950-4_37
关键词: Lamellar structure 、 Crystallization 、 Temperature jump 、 Ether 、 X-ray 、 Peek 、 Crystallography 、 Materials science 、 Small-angle X-ray scattering 、 Crystallinity 、 Organic chemistry
摘要: Time-resolved small-angle X-ray scattering (SAXS) experiments were conducted to study the crystallization and melting behavior of poly(aryl ether ketone), PEEK, using synchrotron radiation a dual-chamber temperature jump apparatus. The long period L, invariant Q lamellar thickness lc determined from correlation function data. During crystallization, it was found that L decreased, increased, lC remained about constant with time. decrease in explained by insertion within stacks, whereas increase attributed total degree crystallinity. melting, increased two-stage fashion: small below lower double-melting large above that. Both also but showed maximum before higher temperature. These results support model two populations lamellae different PEEK (proposed Bassett et al. [1]): primary are developed first bundle-like stacks narrower secondary inserted later lamellae.
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sci-hub.st 参考文章(19)
E. Rubenstein, Ernst-Eckhard Koch, G. S. Brown, D. E. Moncton, M. Koch, Geoffrey V. Marr, 節郎 江橋, Handbook on synchrotron radiation ApOpt. ,vol. 31, pp. 2399- 2400 ,(1983)
H. H. Song, D. Q. Wu, Benjamin Chu, M. Satkowski, M. Ree, R. S. Stein, J. C. Phillips, Time-resolved small-angle x-ray scattering of a high-density polyethylene/low-density polyethylene blend Macromolecules. ,vol. 23, pp. 2380- 2384 ,(1990) , 10.1021/MA00210A040
Youngchul Lee, Roger S. Porter, Double-melting behavior of poly(ether ether ketone) Macromolecules. ,vol. 20, pp. 1336- 1341 ,(1987) , 10.1021/MA00172A028
Herve Marand, Abaneshwar Prasad, On the observation of a new morphology in poly(arylene ether ether ketone). A further examination of the double endothermic behavior of poly(arylene ether ether ketone) Macromolecules. ,vol. 25, pp. 1731- 1736 ,(1992) , 10.1021/MA00032A017
Andrew J. Lovinger, D. D. Davis, Electron-microscopic investigation of the morphology of a melt-crystallized polyaryletherketone Journal of Applied Physics. ,vol. 58, pp. 2843- 2853 ,(1985) , 10.1063/1.335856
H. H. Song, R. S. Stein, D. Q. Wu, M. Ree, J. C. Phillips, A. LeGrand, B. Chu, Time-resolved SAXS on crystallization of a low-density polyethylene/high density polyethylene polymer blend Macromolecules. ,vol. 21, pp. 1180- 1182 ,(1988) , 10.1021/MA00182A057
Andrew J. Lovinger, Steven D. Hudson, Don D. Davis, High-temperature crystallization and morphology of poly(aryl ether ether ketone) Macromolecules. ,vol. 25, pp. 1752- 1758 ,(1992) , 10.1021/MA00032A020
D BASSETT, R OLLEY, I ALRAHEIL, On crystallization phenomena in PEEK Polymer. ,vol. 29, pp. 1745- 1754 ,(1988) , 10.1016/0032-3861(88)90386-2
Stephen J Spells, Mary J Hill, Morphological changes on annealing polyethylene single crystals Polymer. ,vol. 32, pp. 2716- 2723 ,(1991) , 10.1016/0032-3861(91)90098-4
Youngchul Lee, Roger S. Porter, J. S. Lin, On the double-melting behavior of poly(ether ether ketone) Macromolecules. ,vol. 22, pp. 1756- 1760 ,(1989) , 10.1021/MA00194A043