High resolution molecular gas phase photoelectron spectra of core levels using synchrotron radiation - vibrational and ligand field splittings

作者: J.D. Bozek , J.N. Cutler , G.M. Bancroft , L.L. Coatsworth , K.H. Tan

DOI: 10.1016/0009-2614(90)87001-8

关键词: XenonSynchrotron radiationSpectral lineAtomic physicsPhotoemission spectroscopyLigand field theorySpectrometerAugerResolution (electron density)ChemistryPhysical and Theoretical ChemistryGeneral Physics and Astronomy

摘要: Abstract A new high resolution photoelectron spectrometer designed for core level studies of gas phase volatile and involatile compounds using synchrotron radiation is briefly described. Xenon NOO Auger spectral linewidths 0.13 eV indicate that the electron 4 ligand field splitting Xe 4d XeF 2 .

参考文章(26)
E Ishiguro, S Iwata, A Mikuni, Y Suzuki, H Kanamori, T Sasaki, The high-resolution photoabsorption spectra of PH3, PF3, PCl3 and PBr3 in the XUV region Journal of Physics B. ,vol. 20, pp. 4725- 4739 ,(1987) , 10.1088/0022-3700/20/18/013
William Hayes, Frederick C. Brown, Absorption by Some Molecular Gases in the Extreme Ultraviolet Physical Review A. ,vol. 6, pp. 21- 30 ,(1972) , 10.1103/PHYSREVA.6.21
G. Michael Bancroft, David K. Creber, Harold Basch, Valence and core electron energies in alkyl cadmium compounds fromabinitiocalculations and photoelectron spectra: Electric field gradients in gas phase Cd compounds The Journal of Chemical Physics. ,vol. 67, pp. 4891- 4897 ,(1977) , 10.1063/1.434670
G.K. Wertheim, D.N.E. Buchanan, Crystal field splitting of core levels in β-Sn Solid State Communications. ,vol. 69, pp. 689- 692 ,(1989) , 10.1016/0038-1098(89)90063-X
C. T. Chen, F. Sette, Performance of the Dragon soft x‐ray beamline (invited) Review of Scientific Instruments. ,vol. 60, pp. 1616- 1621 ,(1989) , 10.1063/1.1141044
Christian Gähwiller, Frederick C. Brown, Photoabsorption near the L I I , I I I Edge of Silicon and Aluminum Physical Review B. ,vol. 2, pp. 1918- 1925 ,(1970) , 10.1103/PHYSREVB.2.1918
F. J. Comes, R. Haensel, U. Nielsen, W. H. E. Schwarz, Spectra of the xenon fluorides XeF2 and XeF4 in the far uv region The Journal of Chemical Physics. ,vol. 58, pp. 516- 529 ,(1973) , 10.1063/1.1679232
U. Gelius, S. Svensson, H. Siegbahn, E. Basilier, Å. Faxälv, K. Siegbahn, Vibrational and lifetime line broadenings in ESCA Chemical Physics Letters. ,vol. 28, pp. 1- 7 ,(1974) , 10.1016/0009-2614(74)80002-3