Metal-catalyzed radical polyaddition as a novel polymer synthetic route

作者: Kotaro Satoh , Masato Mizutani , Masami Kamigaito

DOI: 10.1039/B616598B

关键词: MoleculeMetal catalystCarbonCatalysisPolymerPolymer chemistryDouble bondChemistryPhotochemistryMonomerMetal

摘要: A new class of polymerizations was developed via metal-catalyzed C–C bond forming radical polyaddition; the monomers were designed to have a reactive C–Cl bond, which can be activated by metal catalysts generate carbon species, along with CC double generated from another molecule adds form backbone polymer an inactive pendant.

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