Preparation and structural characterization of a novel dicopper(II) complex with a terminal hydroxide: a structural model of an active site in phosphohydrolases
作者： Hidekazu Arii , Yasuhiro Funahashi , Koichiro Jitsukawa , Hideki Masuda
DOI: 10.1039/B303787H
关键词: Photochemistry 、 Hydroxide 、 Magnetic susceptibility 、 Metal 、 Intramolecular force 、 Steric effects 、 Active site 、 Chemistry 、 Crystallography 、 Ligand 、 Absorption (chemistry)
摘要: As an intermediate model for active dinuclear metal sites in phosphohydrolases, a novel dicopper(II) complex with terminal hydroxide has been prepared using new dinucleating ligand intramolecular hydrogen-bonding N–H and sterically hindered tert-butyl groups. It characterized by X-ray structure analysis, magnetic susceptibility, ESR electronic absorption spectroscopies.
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