Basic approach to development of environment-friendly oxidation catalyst materials. Mononuclear hydroperoxo copper(II) complexes
作者： Syuhei Yamaguchi , Hideki Masuda
DOI: 10.1016/J.STAM.2004.06.004
关键词:
摘要: In this review, basic studies on the binding and activation of dioxygen species by copper complexes with originally designed ligands are described as initial step for development environment-friendly oxidation catalyst. order to examine stability/reactivity such a mononuclear copper(II) complex, some hydroperoxide ion have been constructed using that prepared basis active center structures metalloenzymes, effects (i) hydrogen bond, (ii) hydrophobic sphere, (iii) coordination structure around metal, (iv) coordinating atoms investigated systematically, from point view synthetic, spectroscopic, structural, kinetic, theoretical chemistries. It has also found out decomposition rate constants O–O bond strengths hydroperoxo strongly correlated.
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