Influence of surface Si–Ag bonds on photoluminescence of porous silicon

作者: Y. W. Lu , X. W. Du , J. Sun , X. Han , S. A. Kulinich

DOI: 10.1063/1.2353397

关键词: Light emissionInorganic chemistryMaterials sciencePorous mediumNanocrystalline siliconPhotoluminescencePorous siliconDeposition (law)MetalSilicon

摘要: Porous silicon with surface Si–Ag bonds was prepared by depositing Ag on conventional electrochemically porous using electrodeposition method, and the influence of surface-bonded photoluminescence properties material studied. Photoluminescence intensity increases amount formed during electrochemical deposition. Further treatment leads to increased amounts Ag–O Ag–Ag surface. Such layers oxygen-bonded metallic are shown retard light emission from silicon.

参考文章(18)
P RAM, J SINGH, T. R RAMAMOHAN, S VENKATACHALAM, V. P SUNDARSINGH, Surface properties of electrodeposited a-Si:C:H:F thin films by X-ray photoelectron spectroscopy Journal of Materials Science. ,vol. 32, pp. 6305- 6310 ,(1997) , 10.1023/A:1018653631062
David A. Zatko, John W. Prather, Photoelectron spectroscopy verification of highly charged silver ions in the ethylenebis(biguanide)-silver(III) complex ion Journal of Electron Spectroscopy and Related Phenomena. ,vol. 2, pp. 191- 197 ,(1973) , 10.1016/0368-2048(73)80008-8
Q.W. Chen, X. Li, Y. Zhang, Improvement mechanism of photoluminescence in iron-passivated porous silicon Chemical Physics Letters. ,vol. 343, pp. 507- 512 ,(2001) , 10.1016/S0009-2614(01)00762-X
L.T Canham, T.I Cox, A Loni, A.J Simons, Progress towards silicon optoelectronics using porous silicon technology Applied Surface Science. ,vol. 102, pp. 436- 441 ,(1996) , 10.1016/0169-4332(96)00094-3
J. E. Bateman, R. D. Eagling, B. R. Horrocks, A. Houlton, A Deuterium Labeling, FTIR, and Ab Initio Investigation of the Solution-Phase Thermal Reactions of Alcohols and Alkenes with Hydrogen-Terminated Silicon Surfaces The Journal of Physical Chemistry B. ,vol. 104, pp. 5557- 5565 ,(2000) , 10.1021/JP000080T
Victor S-Y Lin, Kianoush Motesharei, Keiki-Pua S Dancil, Michael J Sailor, M Reza Ghadiri, A Porous Silicon-Based Optical Interferometric Biosensor Science. ,vol. 278, pp. 840- 843 ,(1997) , 10.1126/SCIENCE.278.5339.840
E. Yablonovitch, D. L. Allara, C. C. Chang, T. Gmitter, T. B. Bright, Unusually low surface-recombination velocity on silicon and germanium surfaces. Physical Review Letters. ,vol. 57, pp. 249- 252 ,(1986) , 10.1103/PHYSREVLETT.57.249
Yang Liu, Tu Pei Chen, Yong Qing Fu, Man Siu Tse, Jang-Hsing Hsieh, PF Ho, YC Liu, A study on Si nanocrystal formation in Si-implanted SiO2 films by x-ray photoelectron spectroscopy Journal of Physics D. ,vol. 36, ,(2003) , 10.1088/0022-3727/36/19/L02
Wolfgang Lotz, Electron Binding Energies in Free Atoms Journal of the Optical Society of America. ,vol. 60, pp. 206- 210 ,(1970) , 10.1364/JOSA.60.000206