In SituStructural Study of 4V-Range Lithium Extraction/Insertion in Fluorine-Substituted LiMn2O4
作者： M.R. Palacı́n , F. Le Cras , L. Seguin , M. Anne , Y. Chabre
关键词: Crystal structure 、 Oxide 、 X-ray crystallography 、 Lithium 、 Extraction (chemistry) 、 Spinel 、 Inorganic chemistry 、 Analytical chemistry 、 Orthorhombic crystal system 、 Formula unit 、 Chemistry
摘要: The structural features accompanying the lithium extraction/insertion process in a fluorine-substituted spinel oxide with formula LiMn2(O3.74F0.26) were studiedin situusing Bellcore-type plastic batteries directly placed synchrotron X-ray beam. initial material contains two phases, cubic and slightly orthorhombically distorted one (major phase). It becomes entirely on extraction of 0.17 Li atoms per unit. reaction around 4 V vs Li/Li+can be divided into three regions as function contentx: (1) single-phase range for 0.59≤x≤0.83, (2) two-phase 0.23≤x≤0.59 equilibrium potential 4.122 V, (3) narrow III 0.18≤x≤0.23. These domains are fully reversible. With exception presence orthorhombic distortion, main so-called electrochemical plateau very similar to those stoichiometric LixMn2O4.
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sci-hub.se 参考文章(17)
W. Liu, K. Kowal, G. C. Farrington, Mechanism of the electrochemical insertion of lithium into LiMn{sub 2}O{sub 4} spinels Journal of The Electrochemical Society. ,vol. 145, pp. 459- 465 ,(1998) , 10.1149/1.1838285
Yuan Gao, J. R. Dahn, Synthesis and Characterization of Li1 + x Mn2 − x O 4 for Li‐Ion Battery Applications Journal of The Electrochemical Society. ,vol. 143, pp. 100- 114 ,(1996) , 10.1149/1.1836393
G.G. Amatucci, C.N. Schmutz, A. Blyr, C. Sigala, A.S. Gozdz, D. Larcher, J.M. Tarascon, Materials' effects on the elevated and room temperature performance of CLiMn2O4 Li-ion batteries Journal of Power Sources. ,vol. 69, pp. 11- 25 ,(1997) , 10.1016/S0378-7753(97)02542-1
J. Rodríguez-Carvajal, G. Rousse, C. Masquelier, M. Hervieu, Electronic Crystallization in a Lithium Battery Material: Columnar Ordering of Electrons and Holes in the Spinel LiMn 2 O 4 Physical Review Letters. ,vol. 81, pp. 4660- 4663 ,(1998) , 10.1103/PHYSREVLETT.81.4660
Kenichi Oikawa, Takashi Kamiyama, Fujio Izumi, Bryan C Chakoumakos, Hiromasa Ikuta, Masataka Wakihara, Jianqi Li, Yoshio Matsui, Structural phase transition of the spinel-type oxide LiMn2O4 Solid State Ionics. ,vol. 109, pp. 35- 41 ,(1998) , 10.1016/S0167-2738(98)00073-3
J.-M. Tarascon, A.S. Gozdz, C. Schmutz, F. Shokoohi, P.C. Warren, Performance of Bellcore's plastic rechargeable Li-ion batteries Solid State Ionics. ,vol. 86, pp. 49- 54 ,(1996) , 10.1016/0167-2738(96)00330-X
M. N. Richard, I. Koetschau, J. R. Dahn, A Cell for In Situ X‐Ray Diffraction Based on Coin Cell Hardware and Bellcore Plastic Electrode Technology Journal of The Electrochemical Society. ,vol. 144, pp. 554- 557 ,(1997) , 10.1149/1.1837447
Yongyao Xia, Masaki Yoshio, An Investigation of Lithium Ion Insertion into Spinel Structure Li‐Mn‐O Compounds Journal of The Electrochemical Society. ,vol. 143, pp. 825- 833 ,(1996) , 10.1149/1.1836544
J. Barker, Three Electrode Electrochemical Voltage Spectroscopy (TEVS): evaluation of a model lithium ion system Electrochimica Acta. ,vol. 40, pp. 1603- 1608 ,(1995) , 10.1016/0013-4686(95)00090-2
D GUYOMARD, J TARASCON, The carbon/Li1+xMn2O4 system Solid State Ionics. ,vol. 69, pp. 222- 237 ,(1994) , 10.1016/0167-2738(94)90412-X