AC conductivity and dielectric properties of (Bi,Na)TiO3–BaTiO3 lead free ceramics

作者: Woo-Seok Kang , Sang-Kwon Lee , Jung-Hyuk Koh

DOI: 10.1016/J.CERAMINT.2015.01.147

关键词: Dissipation factorDielectricPiezoelectricityMaterials scienceCoercivityCurie temperatureCeramicAnalytical chemistryX-ray crystallographyFerroelectricity

摘要: Abstract (Bi,Na)TiO 3 (BNT) based ceramics have been extensively investigated for electronic device applications. BNT is ferroelectric material with ABO perovskite structure. high Curie temperature ( T c =320 °C) and remanent polarization P r =38 µC/cm 2 ). Despite its relatively coercive field E =7.3 kV/mm) low piezoelectric constant d 33 =83 pC/N). Temperature frequency dependent relative dielectric permittivity loss tangent can play an important role in the performance. To analyze characteristics across wide (303–403 K) range (1 kHz to 3 MHz), AC conductivities of (1− x )(Bi 0.5 Na TiO )− (BaTiO ) =0, 0.02, 0.04, 0.06, 0.08, or 0.10 were measured analyzed. The conduction mechanism was evaluated through simulations calculations on Arrhenius-type equation.

参考文章(24)
S.R Shannigrahi, R.N.P Choudhary, H.N Acharya, Structural and dielectric properties of Nd modified Pb(Zr0.60Ti0.40)O3 ceramics Materials Science and Engineering B-advanced Functional Solid-state Materials. ,vol. 60, pp. 31- 39 ,(1999) , 10.1016/S0921-5107(99)00002-1
S.H. Choy, H.L.W. Chan, Nonlinear behavior of BNT-based lead-free piezoceramics under various ac fields Current Applied Physics. ,vol. 11, pp. 869- 877 ,(2011) , 10.1016/J.CAP.2010.12.011
Eric Cross, Materials science: Lead-free at last Nature. ,vol. 432, pp. 24- 25 ,(2004) , 10.1038/NATURE03142
Marin Cernea, Carmen Galassi, Bogdan S. Vasile, Claudio Capiani, Ciceron Berbecaru, Ioana Pintilie, Lucian Pintilie, Structural, dielectric, and piezoelectric properties of fine-grained NBT–BT0.11 ceramic derived from gel precursor Journal of the European Ceramic Society. ,vol. 32, pp. 2389- 2397 ,(2012) , 10.1016/J.JEURCERAMSOC.2012.02.021
A.V. Shil'nikov, A.V. Sopit, A.I. Burkhanov, A.G. Luchaninov, The dielectric response of electrostrictive (1-x) PMN-xPZT ceramics Journal of The European Ceramic Society. ,vol. 19, pp. 1295- 1297 ,(1999) , 10.1016/S0955-2219(98)00423-3
Susant Kumar Acharya, Sang-Kwon Lee, Jung-Hwan Hyung, Yun-Ho Yang, Bok-Hee Kim, Byung-Guk Ahn, Ferroelectric and piezoelectric properties of lead-free BaTiO3 doped Bi0.5Na0.5TiO3 thin films from metal-organic solution deposition Journal of Alloys and Compounds. ,vol. 540, pp. 204- 209 ,(2012) , 10.1016/J.JALLCOM.2012.06.071
Marin Cernea, Ecaterina Andronescu, Roxana Radu, Fabio Fochi, Carmen Galassi, Sol–gel synthesis and characterization of BaTiO3-doped (Bi0.5Na0.5)TiO3 piezoelectric ceramics Journal of Alloys and Compounds. ,vol. 490, pp. 690- 694 ,(2010) , 10.1016/J.JALLCOM.2009.10.140
Jean-François Trelcat, Christian Courtois, Mohamed Rguiti, Anne Leriche, Paul-Henri Duvigneaud, Tiriana Segato, Morphotropic phase boundary in the BNT-BT-BKT system Ceramics International. ,vol. 38, pp. 2823- 2827 ,(2012) , 10.1016/J.CERAMINT.2011.11.053