QSARs and PARs for biodegradation of PCBs.
作者： J.R. Parsons , L.C.M. Commandeur , H.E. van Eyseren , H.A.J. Govers
DOI: 10.1016/0048-9697(91)90184-G
关键词: Reactivity (chemistry) 、 Organic chemistry 、 Chemistry 、 Permeation 、 Enzyme binding 、 Partition coefficient 、 Biodegradation 、 Chlorine 、 Membrane 、 Reaction rate constant 、 Environmental chemistry
摘要: Relationships between the biodegradation rate constants of a number polychlorinated biphenyls (PCBs) and hydrophobic electronic structural parameters are compared. There is no simple relationship with octanol-water partition coefficients, indicating that rates PCBs probably not determined by their permeation through bacterial membranes. Biodegradation correlated much better both properties chlorine substituents, which suggests reactivity possibly enzyme binding control rates.
harvard.edu
elsevier.com
sci-hub.se 参考文章(15)
J.R. Parsons, D.T.H.M. Sijm, Biodegradation kinetics of polychlorinated biphenyls in continuous cultures of a strain Chemosphere. ,vol. 17, pp. 1755- 1766 ,(1988) , 10.1016/0045-6535(88)90104-X
Ronald Unterman, Donna L. Bedard, Michael J. Brennan, Lawrence H. Bopp, Frank J. Mondello, Ronald E. Brooks, David P. Mobley, John B. McDermott, Charles C. Schwartz, David K. Dietrich, Biological approaches for polychlorinated biphenyl degradation. Basic life sciences. ,vol. 45, pp. 253- 269 ,(1988) , 10.1007/978-1-4899-0824-7_17
Corwin Herman Hansch, Albert Leo, Substituent constants for correlation analysis in chemistry and biology Published in <b>1979</b> in New York NY) by Wiley. ,(1979)
Kensuke Furukawa, Kenzo Tonomura, Akira Kamibayashi, Effect of Chlorine Substitution on the Biodegradability of Polychlorinated Biphenyls Applied and Environmental Microbiology. ,vol. 35, pp. 223- 227 ,(1978) , 10.1128/AEM.35.2.223-227.1978
J N Bateman, B Speer, L Feduik, R A Hartline, Naphthalene association and uptake in Pseudomonas putida. Journal of Bacteriology. ,vol. 166, pp. 155- 161 ,(1986) , 10.1128/JB.166.1.155-161.1986
J.R. Parsons, H.A.J. Govers, Quantitative structure-activity relationships for biodegradation Ecotoxicology and Environmental Safety. ,vol. 19, pp. 212- 227 ,(1990) , 10.1016/0147-6513(90)90069-H
G.L. Flynn, S.H. Yalkowsky, Correlation and prediction of mass transport across membranes I: Influence of alkyl chain length on flux‐determining properties of barrier and diffusant Journal of Pharmaceutical Sciences. ,vol. 61, pp. 838- 852 ,(1972) , 10.1002/JPS.2600610603
Wan Ying Shiu, Donald Mackay, A Critical Review of Aqueous Solubilities, Vapor Pressures, Henry’s Law Constants, and Octanol–Water Partition Coefficients of the Polychlorinated Biphenyls Journal of Physical and Chemical Reference Data. ,vol. 15, pp. 911- 929 ,(1986) , 10.1063/1.555755
P. Pitter, Correlation of Microbial Degradation Rates with the Chemical Structure Acta Hydrochimica Et Hydrobiologica. ,vol. 13, pp. 453- 460 ,(1985) , 10.1002/AHEH.19850130408
Walter Reineke, Hans-Joachim Knackmuss, Chemical structure and biodegradability of halogenated aromatic compounds substituent effects on 1,2-dioxygenation of benzoic acid Biochimica et Biophysica Acta. ,vol. 542, pp. 412- 423 ,(1978) , 10.1016/0304-4165(78)90372-0