作者: J.H. Saunders , F. Dobinson
DOI: 10.1016/S0069-8040(08)70053-0
关键词: Kinetics 、 Computational chemistry 、 Condensation polymer 、 Chemical reaction 、 Molar mass distribution 、 Organic chemistry 、 Chemistry 、 Emulsion
摘要: Publisher Summary This chapter presents the experimentally determined kinetic data that are available on polycondensation reactions and discusses their mechanisms. The statistics of helps to understand kinetics. rates polycondensations in melt, solution emulsion controlled primarily by kinetics between functional groups involved. Interfacial solid-state largely dependent rate diffusion reacting species site reaction. statistical development equations related molecular weight, weight distribution, gelation applies those limited chemical reactions, rather than system. However, independent actual particular these gives an extensive treatment for reactions.