The synthesis of novel 3-substituted pyrrole monomers possessing chiral side groups: a study of their chemical polymerisation and the assessment of their chiral discrimination properties

作者: Benjamin P.J de Lacy Costello , Norman M Ratcliffe , Pennadam S Sivanand

DOI: 10.1016/S0379-6779(02)01247-X

关键词: Conductive polymerMonomerGas detectorEnantiomerPhase (matter)PolymerizationChemistryPolymerPolymer chemistryPyrrole

摘要: Novel 3-substituted pyrrole monomers possessing chiral side groups were synthesised. These compounds successfully polymerised with ferric salts and the polymer materials fabricated into sensors. The sensors found to elicit differential changes in electrical resistance mass, when exposed different enantiomers vapour phase.

参考文章(27)
Nathan S. Lewis, Margaret A. Ryan, Low power, lightweight vapor sensing using arrays of conducting polymer composite chemically-sensitive resistors. Enantiomer. ,vol. 6, pp. 159- 170 ,(2001)
G. Gustafsson, I. Lundström, B. Liedberg, C.R. Wu, O. Inganäs, O. Wennerström, The interaction between ammonia and poly(pyrrole) Synthetic Metals. ,vol. 31, pp. 163- 179 ,(1989) , 10.1016/0379-6779(89)90812-6
Mira. Josowicz, Jiri. Janata, Suspended gate field effect transistor modified with polypyrrole as alcohol sensor Analytical Chemistry. ,vol. 58, pp. 514- 517 ,(1986) , 10.1021/AC00294A003
Tetsuro Hanawa, Susumu Kuwabata, Hiroshi Yoneyama, Gas sensitivity of polypyrrole films to NO2 Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. ,vol. 84, pp. 1587- 1592 ,(1988) , 10.1039/F19888401587
Manuel Salmón, Miguel Saloma, Gerard Bidan, E.M. Genies, Route to chemically modified chiral electrodes: synthesis and properties of optically active pyrrole monomers Electrochimica Acta. ,vol. 34, pp. 117- 120 ,(1989) , 10.1016/0013-4686(89)87075-6
Bernhard Neises, Wolfgang Steglich, Simple Method for the Esterification of Carboxylic Acids Angewandte Chemie. ,vol. 17, pp. 522- 524 ,(1978) , 10.1002/ANIE.197805221
G Gustafsson, I Lundström, The effect of ammonia on the physical properties of polypyrrole Synthetic Metals. ,vol. 21, pp. 203- 208 ,(1987) , 10.1016/0379-6779(87)90087-7
D. Delabouglise, F. Garnier, Chiral metals: amino acid-substituted conducting polypyrroles Synthetic Metals. ,vol. 39, pp. 117- 120 ,(1990) , 10.1016/0379-6779(90)90205-Y
Mira. Josowicz, Jiri. Janata, Kevin. Ashley, Stanley. Pons, Electrochemical and ultraviolet−visible spectroelectrochemical investigation of selectivity of potentiometric gas sensors based on polypyrrole Analytical Chemistry. ,vol. 59, pp. 253- 258 ,(1987) , 10.1021/AC00129A008
Ken-ichi Shinohara, Toshiki Aoki, Takashi Kaneko, Eizo Oikawa, Syntheses and enantioselective recognition of chiral poly(phenyleneethynylene)s bearing bulky optically active menthyl groups Polymer. ,vol. 42, pp. 351- 355 ,(2001) , 10.1016/S0032-3861(00)00391-8