Synthesis and polymerization studies of 3-(+) and (−)-menthyl carboxylate pyrroles
作者： Richard C. Foitzik , Elspeth K. Bowen , Amelia M. Taylor , Frederick M. Pfeffer , Akif Kaynak
DOI: 10.1016/J.SYNTHMET.2007.09.003
关键词:
摘要: The synthesis of 3-(−)- and 3-(+)-menthyl carboxylate pyrrole was achieved in four high yielding steps, including the triisopropylsilyl (TIPS) protection nitrogen, bromination 3-position, lithium halogen exchange followed by reaction with menthyl chloroformate, finally de-protection. Chemical polymerization both TIPS protected, non-protected, pyrroles performed resulting polymers exhibited conductivity ranging from 0.6 to 2.3 S/cm. Polymerization 3-menthyl-N-TIPS on surface wool using solution mist methods.
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