Low‐Temperature Synthesis of Nanocrystalline Titanium Nitride via a Benzene–Thermal Route
作者： Junqing Hu , Qingyi Lu , Kaibin Tang , Shuhong Yu , Yitai Qian
DOI: 10.1111/J.1151-2916.2000.TB01212.X
关键词: Tin 、 Nitride 、 Materials science 、 Titanium nitride 、 Transmission electron microscopy 、 Analytical chemistry 、 Thermal treatment 、 Lattice constant 、 Atomic ratio 、 Nanocrystalline material 、 Metallurgy
摘要: A benzene–thermal reaction of TiCl4 and NaN3 at 350°–380°C was conducted for the preparation nanocrystalline TiN. Powder X-ray diffractometry patterns indicated that powder cubic-phase TiN with a lattice constant a= 4.23656 A. Transmission electron microscopy images showed powders consisted uniform spherical particles an average diameter 50 nm. The binding energies Ti 2p3/2 N 1s core levels positions 454.85 397.1 eV, respectively, Ti:N atomic ratio 1.08:1.00 were detected by photoelectron spectra. possible formation mechanism proposed.
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