Polarized Raman optical activity in methyl antisymmetric deformations: Influence of heteroatom Rydberg orbitals
作者： L.D. Barron , L. Hecht , P.L. Polavarapu
DOI: 10.1016/0009-2614(89)87458-5
关键词: Heteroatom 、 Raman optical activity 、 Rydberg formula 、 Chemistry 、 Polarizability 、 Photochemistry 、 Antisymmetric relation 、 Raman spectroscopy 、 Rydberg state 、 Quadrupole 、 Molecular physics 、 Physical and Theoretical Chemistry 、 General Physics and Astronomy
摘要: Large deviations from the factor of 2 in ratio polarized to depolarized Raman optical activity intensities methyl antisymmetric deformations 1-phenylethanol and 1-phenylethylthiol are reported. It is suggested that these might originate large electric quadrupole contributions induced by excited-state interactions involving heteroatom Rydberg p orbitals on other parts molecule. Such appear undermine bond polarizability theory intensities.
core.ac.uk
harvard.edu
elsevier.com
sci-hub.se 参考文章(10)
L.D. Barron, A.D. Buckingham, Rayleigh and Raman scattering from optically active molecules Molecular Physics. ,vol. 20, pp. 1111- 1119 ,(1971) , 10.1080/00268977100101091
L.D. Barron, J.R. Escribano, J.F. Torrance, Polarized raman optical activity and the bond polarizability model Molecular Physics. ,vol. 57, pp. 653- 660 ,(1986) , 10.1080/00268978600100481
L.D. Barron, J.R. Escribano, Polarized raman optical activity of β-pinene: electric quadrupole contributions Chemical Physics Letters. ,vol. 126, pp. 461- 464 ,(1986) , 10.1016/S0009-2614(86)80136-1
W. Hug, A. Kamatari, K. Srinivasan, H.-J. Hansen, H.-R. Sliwka, The vibrational Raman optical activity of deuterated 1-methylindanes Chemical Physics Letters. ,vol. 76, pp. 469- 474 ,(1980) , 10.1016/0009-2614(80)80649-X
C.N. Su, T.A. Keiderling, Vibrational circular dichroism of methyl deformation modes Chemical Physics Letters. ,vol. 77, pp. 494- 499 ,(1981) , 10.1016/0009-2614(81)85193-7
L. D. Barron, A. D. Buckingham, A simple two-group model for Rayleigh and Raman optical activity Journal of the American Chemical Society. ,vol. 96, pp. 4769- 4773 ,(1974) , 10.1021/JA00822A008
James R. Durig, Vibrational spectra and structure. Vibrational spectra and structure. ,(1972)
L. Hecht, B. Jordanov, B. Schrader, Stokes Mueller Treatment of Artifacts in Natural Raman Optical Activity Applied Spectroscopy. ,vol. 41, pp. 295- 307 ,(1987) , 10.1366/000370287774986868
L. D. Barron, J. F. Torrance, D. J. Cutler, A new multichannel Raman optical activity instrument Journal of Raman Spectroscopy. ,vol. 18, pp. 281- 287 ,(1987) , 10.1002/JRS.1250180410
E. Bright Wilson, The Normal Modes and Frequencies of Vibration of the Regular Plane Hexagon Model of the Benzene Molecule Physical Review. ,vol. 45, pp. 706- 714 ,(1934) , 10.1103/PHYSREV.45.706