Polarized raman optical activity of β-pinene: electric quadrupole contributions
作者： L.D. Barron , J.R. Escribano
DOI: 10.1016/S0009-2614(86)80136-1
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摘要: A comparison of the polarized and depolarized Raman optical activity spectra β-pinene, obtained with a new multichannel instrument, provides evidence for large electric-dipole-electric-quadrupole contributions. consideration symmetry characteristics π★ ← π transition shows that such contributions are expected from deformations an olefinic group local C2v symmetry.
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