Magnetic circular dichroism in x-ray resonant Raman scattering in perpendicular geometry fromCoFe2O4and Co metal: A comparison of valence and inner-shell channels

作者: L. Braicovich , G. van der Laan , G. Ghiringhelli , A. Tagliaferri , N. B. Brookes

DOI: 10.1103/PHYSREVB.66.174435

关键词: Photon energyMagnetic circular dichroismVibrational circular dichroismX-ray magnetic circular dichroismRaman scatteringCircular dichroismDichroismLinear dichroismGeometryPhysics

摘要: We present results on resonant Raman scattering (RRS) in perpendicular geometry excited with circularly polarized x rays at the Co L 3 , 2 edges CoFe O 4 (Co ferrite) and metal. In this incident x-ray beam is to magnetization magnetic dichroism only RRS not absorption. compare 3s-RRS channel terminating an inner shell 3s hole extra 3d electron (2p 6 n →2p 5 + 1 ) 3d-RRS ending a electron-hole pair → 2p ). The work based measurement of spectra vs photon energy integrated over scattered energy. both samples inner-shell about order magnitude larger than that valence channel. result explained by theory fast-collision approximation. show provides general way choose optimum study geometry. impact briefly discussed.

参考文章(25)
C. T. Chen, F. Sette, Y. Ma, S. Modesti, Soft-x-ray magnetic circular dichroism at the L 2 , 3 edges of nickel Physical Review B. ,vol. 42, pp. 7262- 7265 ,(1990) , 10.1103/PHYSREVB.42.7262
B. T. Thole, H. A. Dürr, G. van der Laan, Core hole polarization in x-ray absorption studied by magnetic circular dichroism in 2p3p3p resonant photoemission. Physical Review Letters. ,vol. 74, pp. 2371- 2374 ,(1995) , 10.1103/PHYSREVLETT.74.2371
F. Borgatti, P. Ferriani, G. Ghringhelli, A. Tagliaferri, B. De Michelis, C. M. Bertoni, N. B. Brookes, L. Braicovich, Magnetic circular dichroism in resonant x-ray emission from impurities: Results at the L-2,(3) edges of Mn in Ni Physical Review B. ,vol. 65, pp. 094406-1- 094406-10 ,(2002) , 10.1103/PHYSREVB.65.094406
C. M. Schneider, D. Venus, J. Kirschner, Strong x-ray magnetic circular dichroism in a "forbidden geometry" observed via photoemission. Physical Review B. ,vol. 45, pp. 5041- 5044 ,(1992) , 10.1103/PHYSREVB.45.5041
C. Dallera, E. Puppin, G. Trezzi, N. Incorvaia, A. Fasana, L. Braicovich, N. B. Brookes, J. B. Goedkoop, Soft X‐ray Emission Spectroscopy at ESRF Beamline 26 Based on a Helical Undulator Journal of Synchrotron Radiation. ,vol. 3, pp. 231- 238 ,(1996) , 10.1107/S0909049596006061
Gerrit van der Laan, Core-level magnetic circular dichroism as a probe for electron-correlation effects Journal of Electron Spectroscopy and Related Phenomena. ,vol. 117, pp. 89- 101 ,(2001) , 10.1016/S0368-2048(01)00247-X
S Eisebitt, J Lüning, J.-E Rubensson, D Schmitz, S Blügel, W Eberhardt, Dichroism and spin information in soft X-ray emission Solid State Communications. ,vol. 104, pp. 173- 177 ,(1997) , 10.1016/S0038-1098(97)00108-7
L. Paolasini, C. Vettier, F. de Bergevin, F. Yakhou, D. Mannix, A. Stunault, W. Neubeck, M. Altarelli, M. Fabrizio, P. A. Metcalf, J. M. Honig, Orbital Occupancy Order in V2O3: Resonant X-Ray Scattering Results. Physical Review Letters. ,vol. 82, pp. 4719- 4722 ,(1999) , 10.1103/PHYSREVLETT.82.4719
Michio Tokuyama, Irwin Oppenheim, Dynamics of hard-sphere suspensions Physical Review E. ,vol. 50, pp. R16- R19 ,(1994) , 10.1103/PHYSREVE.50.R16
G Van der Laan, B T Thole, Core hole polarization in resonant photoemission Journal of Physics: Condensed Matter. ,vol. 7, pp. 9947- 9988 ,(1995) , 10.1088/0953-8984/7/50/028