IBIL analysis of road dust samples from San Bernardo tunnel.

作者: Gabrio Valotto , Alberto Quaranta , Graziano Guella , Giancarlo Rampazzo

DOI: 10.1016/J.SAA.2013.07.058

关键词: MineralogyFluorescence spectroscopyChemistryParticulatesReference sampleRoad dustAir pollutants

摘要: Abstract Road dust in urban or industrial sites is an important source of atmospheric particulate by re-suspension finer particles that may contain potentially toxic pollutants. In this work Ion Beam Induced Luminescence (IBIL), Nuclear Magnetic Resonance and fluorescence spectroscopy analyses were used to characterize road samples with particle size lower than 250 μm collected on the walls floor ventilation air shaft “Traforo del San Bernardo” highway tunnel. Moreover, for comparison, IBIL performed both some possible anthropic sources matter a reference sample (BCR-723). spectra as function fluence analyzed multivariate approach order identify spectral components evolving different rate. extracted study contribution organic compounds features. Results point out IBIL, here first time analysis, can be applied identification characterizing origin.

参考文章(25)
Jens Wendler, Jens Köster, Jens Götze, Norbert Kasch, Norbert Zisser, Jonas Kley, Dieter Pudlo, Georg Nover, Reinhard Gaupp, Carbonate diagenesis and feldspar alteration in fracture-related bleaching zones (Buntsandstein, central Germany): possible link to CO(2)-influenced fluid-mineral reactions International Journal of Earth Sciences. ,vol. 101, pp. 159- 176 ,(2012) , 10.1007/S00531-011-0671-1
E. Colombo, S. Calusi, R. Cossio, L. Giuntini, A. Lo Giudice, P.A. Mandò, C. Manfredotti, M. Massi, F.A. Mirto, E. Vittone, Recent developments of ion beam induced luminescence at the external scanning microbeam facility of the LABEC laboratory in Florence Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 266, pp. 1527- 1532 ,(2008) , 10.1016/J.NIMB.2007.11.067
Dirk Habermann, Rolf D Neuser, Detlev K Richter, None, Low limit of Mn2+-activated cathodoluminescence of calcite: state of the art Sedimentary Geology. ,vol. 116, pp. 13- 24 ,(1998) , 10.1016/S0037-0738(97)00118-8
J. Pallon, C. Yang, R.J. Utui, M. Elfman, K.G. Malmqvist, P. Kristiansson, K.A. Sjöland, Ionoluminescence technique for nuclear microprobes Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 130, pp. 199- 203 ,(1997) , 10.1016/S0168-583X(97)00182-1
Alberto Quaranta, Recent developments of ion beam induced luminescence : radiation hardness study of thin film plastic scintillators Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 240, pp. 117- 123 ,(2005) , 10.1016/J.NIMB.2005.06.098
Alberto Quaranta, Fabiana Gramegna, Vladimir Kravchuk, Carlo Scian, Radiation damage mechanisms in CsI(Tl) studied by ion beam induced luminescence Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 266, pp. 2723- 2728 ,(2008) , 10.1016/J.NIMB.2008.03.195
Olga Enguita, T. Calderón, M.T. Fernández-Jiménez, P. Beneitez, A. Millan, G. Garcı́a, Damage induced by proton irradiation in carbonate based natural painting pigments Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 219, pp. 53- 56 ,(2004) , 10.1016/J.NIMB.2004.01.027
A. Quaranta, J. Salomon, J.C. Dran, M. Tonezzer, G. Della Mea, Ion beam induced luminescence analysis of painting pigments Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 254, pp. 289- 294 ,(2007) , 10.1016/J.NIMB.2006.11.072
G. Valotto, A. Quaranta, F. Melgani, F. Gonella, G. Rampazzo, Multivariate analysis as a tool for Ion Beam Induced Luminescence (IBIL) spectra interpretation. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 81, pp. 353- 358 ,(2011) , 10.1016/J.SAA.2011.06.022
K.G. Malmqvist, M. Elfman, G. Remond, C. Yang, PIXE and ionoluminescence — A synergetic analytical combination Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. ,vol. 109-110, pp. 227- 233 ,(1996) , 10.1016/0168-583X(95)01212-5