Oxygen addition effects on electrochromic properties of PECVD-synthesized WOxCy films for flexible electrochromic devices

作者: Yung-Sen Lin , Hsuan-Ta Chen , Siang-Syuan Wu

DOI: 10.1007/S10008-010-1015-Y

关键词: ElectrochromismPlasma-enhanced chemical vapor depositionOxideCyclic voltammetryMaterials scienceIndium tin oxideChemical engineeringElectrolyteInorganic chemistryElectrochromic devicesChemical vapor deposition

摘要: An investigation was conducted into the electrochromic properties of organotungsten oxide WOxCy films synthesized onto 60 Ω/□ flexible polyethylene terephthalate/indium tin substrates using low temperature, plasma-enhanced chemical vapor deposition (PECVD) at varying oxygen concentrations. The PECVD-synthesized were proven to offer remarkable performance. Cyclic voltammetry switching measurements revealed that only driving voltages from −1 1 V are needed provide reversible Li+ ion intercalation and de-intercalation in a 0.1 M LiClO4–PC electrolyte. Light modulation with transmittance variation up 72.9% coloration efficiency 62.5 cm2/C wavelength 650 nm obtained.

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