Synthesis of natural products possessing a benzo[b]furan skeleton
作者： Henning Lütjens , Peter J. Scammells
DOI: 10.1016/S0040-4039(98)01371-9
关键词: Skeleton (category theory) 、 Formyl group 、 Chemistry 、 Carbonylation 、 Ailanthoidol 、 Furan 、 Carbon monoxide 、 Organic chemistry
摘要: Abstract A related synthetic strategy has been used to prepare two natural products (XH-14 and ailanthoidol) which possess a benzo[ b ]furan skeleton. The synthesis of XH-14 involved the use palladium-catalyzed cyclization with concomitant carbonylation via insertion carbon monoxide introduce regioselectively formyl group in 3-position.
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