Metal-catalyzed enantioselective allylation in asymmetric synthesis.
作者： Zhan Lu , Shengming Ma
关键词: Enantioselective synthesis 、 Asymmetric induction 、 Regioselectivity 、 Allylic rearrangement 、 Nucleophile 、 Stereochemistry 、 Tsuji–Trost reaction 、 Chemistry 、 Catalysis 、 Metal
摘要: Metal-catalyzed enantioselective allylation, which involves the substitution of allylic metal intermediates with a diverse range different nucleophiles or S(N)2'-type substitution, leads to formation C-H, -C, -O, -N, -S, and other bonds very high levels asymmetric induction. The reaction may tolerate broad functional groups has been applied successfully synthesis many natural products new chiral compounds.
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